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3-三甲基-5,6,7,8-四氢-4H-环庚[d]噻唑-3-高氯酸铵

3-三甲基-5,6,7,8-四氢-4H-环庚[d]噻唑-3-高氯酸铵结构式
3-三甲基-5,6,7,8-四氢-4H-环庚[d]噻唑-3-高氯酸铵结构式
品牌特惠专场
常用名 3-三甲基-5,6,7,8-四氢-4H-环庚[d]噻唑-3-高氯酸铵 英文名 3-Mesityl-5,6,7,8-tetrahydro-4H-cyclohepta[d]thiazol-3-ium perchlorate
CAS号 1062158-63-7 分子量 371.87900
密度 N/A 沸点 N/A
分子式 C17H22ClNO4S 熔点 N/A
MSDS 中文版 美版 闪点 N/A
符号 GHS07
GHS07
信号词 Warning

Palladium-catalyzed C-allylation of benzoins and an NHC-catalyzed three component coupling derived thereof: compatibility of NHC- and Pd-catalysts.

Org. Lett. 10 , 4243-4246, (2008)

A large range of benzoins was successfully applied as C-nucleophiles in the palladium-catalyzed allylic alkylation with several allyl acetates, resulting in functionalized tertiary homoallylic alcohols. A number of unsymmetrical benzoins can be coupled with h...

N-heterocyclic carbene-catalyzed hydroacylation of unactivated double bonds.

J. Am. Chem. Soc. 131 , 14190-14190, (2009)

An intramolecular N-heterocyclic carbene (NHC)-catalyzed hydroacylation of unactivated double bonds is reported. Systematic variation of the catalyst structure revealed an N-mesitylthiazolylidene annulated with a seven-membered ring to be especially reactive....

N-heterocyclic carbene-catalyzed cascade reaction involving the hydroacylation of unactivated alkynes.

J. Am. Chem. Soc. 132 , 5970-5971, (2010)

The N-heterocyclic carbene (NHC)-catalyzed hydroacylation of unactivated alkynes to provide alpha,beta-unsaturated ketones is reported. In addition, a rare case of an efficient and selective dually NHC-catalyzed cascade reaction involving the hydroacylation o...

Diastereoselective Synthesis of Trifluoromethylated γ-Butyrolactones via N-Heterocyclic Carbene-catalyzed Conjugated Umpolung of a,ß-unsaturated Aldehydes. Hirano, K., et al.

Adv. Synth. Catal. 350 , 984-988, (2008)