醋蒽醌
醋蒽醌结构式
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常用名 | 醋蒽醌 | 英文名 | 1,2-aceanthrylenedione |
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| CAS号 | 6373-11-1 | 分子量 | 232.23400 | |
| 密度 | 1.433g/cm3 | 沸点 | 462.6ºC at 760 mmHg | |
| 分子式 | C16H8O2 | 熔点 | 270-273ºC(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 199.7ºC |
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Reactions of Acenaphthenequinone and Aceanthrenequinone with Arenes in Superacid.
Appl. Catal. A Gen. 336(1-2) , 128-132, (2008) The hydroxyalkylation reactions of aceanthrenequinone (6) and acenapthenequinone (7) with a series of arenes have been studied. In reactions with the Br__nsted superacid CF(3)SO(3)H (triflic acid), the condensation products are formed in good yields (58-99%, ... |
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Planarity and constraint of the carbonyl groups in 1,2-diones are determinants for selective inhibition of human carboxylesterase 1.
J. Med. Chem. 50 , 5727-34, (2007) Carboxylesterases (CE) are ubiquitous enzymes responsible for the detoxification of xenobiotics, including numerous clinically used drugs. Therefore, the selective inhibition of these proteins may prove useful in modulating drug half-life and bioavailability.... |
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Deoxygenation of some α-dicarbonyl compounds by tris(diethylamino)phosphine in the presence of fullerene C60.
J. Org. Chem. 76(8) , 2548-57, (2011) The reactions of such cyclic α-diketones as acenaphthenequinone, aceanthrenequinone, and N-alkylisatins, with hexaethyltriaminophosphine in the presence of the fullerene C(60), lead to the formation of methanofullerene derivatives under mild conditions. This ... |
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MacDonald [2 + 2]-type condensation with vicinal diketones: synthesis and properties of novel spiro-tricyclic porphodimethenes.
Org. Lett. 3(15) , 2281-4, (2001) [structure: see text] Acid-catalyzed [2 + 2] condensation reactions of polycyclic aromatic vicinal diketones including aceanthrenequinone, phenathrenequinone, and pyrene-4,5-dione with 5-mesityldipyrromethanes are outlined, and this methodology provides a fle... |