苄异腈
苄异腈结构式
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常用名 | 苄异腈 | 英文名 | Benzyl isocyanate |
|---|---|---|---|---|
| CAS号 | 10340-91-7 | 分子量 | 117.148 | |
| 密度 | 0.962 g/mL at 25 °C(lit.) | 沸点 | 105-106 °C75 mm Hg(lit.) | |
| 分子式 | C8H7N | 熔点 | N/A | |
| MSDS | 中文版 美版 | 闪点 | 175 °F | |
| 符号 |
GHS07 |
信号词 | Warning |
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Smiles rearrangements in Ugi- and Passerini-type couplings: new multicomponent access to O- and N-arylamides.
J. Org. Chem. 72 , 4169, (2007) The use of Smiles rearrangement in Ugi- and Passerini-type couplings with electron-deficient phenols allows very straightforward multicomponent formation of O-aryl- and N-arylamides. Best yields were observed with the highly activated o- and p-nitrophenols, s... |
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Insertion of benzyl isocyanide into a Zr-P bond and rearrangement. Atom-economical synthesis of a phosphaalkene.
Chem. Commun. (Camb.) (40) , 4172-4, (2007) Reaction of (N(3)N)ZrPHPh (N(3)N=N(CH(2)CH(2)NSiMe(3))(3)(3-)) with PhCH(2)N[triple bond]C affords the 1,1-insertion product (N(3)N)Zr[C(PHPh)=NCH(2)Ph], which thermally rearranges to the phosphaalkene-containing complex, (N(3)N)Zr[N(CH(2)Ph)C(H)=PPh]. |
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Synthesis and X-ray studies of ruthenium (II) complexes containing hydrazine and benzyl isocyanide ligands. Owalude SO, et al.
Bull. Chem. Soc. Ethiop. 27(3) , 405-11, (2013)
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