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1-乙酰氧基-1,3-丁二烯

1-乙酰氧基-1,3-丁二烯结构式
1-乙酰氧基-1,3-丁二烯结构式
品牌特惠专场
常用名 1-乙酰氧基-1,3-丁二烯 英文名 1-acetoxy-1,3-butadiene
CAS号 1515-76-0 分子量 112.12700
密度 0.96 g/mL at 20 °C(lit.) 沸点 60-61 °C40 mm Hg(lit.)
分子式 C6H8O2 熔点 N/A
MSDS 美版 闪点 92 °F
符号 GHS02 GHS06
GHS02, GHS06
信号词 Danger

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Intra- and Intermolecular Oxa-Pictet-Spengler Cyclization Strategy for the Enantioselective Synthesis of Deoxy Analogues of (+)-Nanomycin A Methyl Ester, (+)-Eleutherin, (+)-Allo-Eleutherin, and (+)-Thysanone R. T. Sawant, et al.

European J. Org. Chem. 23 , 4442-4449, (2010)

Structure determination of the Diels-Alder product of a ketovinylphosphonate with< i> E</i>-1-acetoxy-1, 3-butadiene. McClure CK, et al.

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Enantio-face control by molecular sieves in the asymmetric Diels-Alder reaction Moharram SM, et al.

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Cis and trans 1-acetoxy-1, 3-butadiene: physical and chemical properties, infrared and ultraviolet spectra. Georgieff KK and Dupré A.

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Gas phase acetoxylation of 1, 3-butadiene over palladium catalysts Part 1: the catalytic activity and structure of Pd-Sb-KOAc catalysts. Shinohara H.

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Radical cation Diels-Alder cycloadditions by visible light photocatalysis.

J. Am. Chem. Soc. 133 , 19350-19353, (2011)

Ruthenium(II) polypyridyl complexes promote the efficient radical cation Diels-Alder cycloaddition of electron-rich dienophiles upon irradiation with visible light. These reactions enable facile [4 + 2] cycloadditions that would be electronically mismatched u...

Synthesis and Diels-Alder reactivity of ortho-carbazolequinones.

Chem. Pharm. Bull. 52(9) , 1114-6, (2004)

Oxidation of 2- and 3-hydroxycarbazoles with Frémy's salt gave the corresponding ortho-carbazolequinones. These molecules react as carbodienophiles in Diels-Alder reaction with 1-acetoxy-1,3-butadiene and 1,3-cyclopentadiene to provide the novel benzocarbazol...