六羰基钼
六羰基钼结构式
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常用名 | 六羰基钼 | 英文名 | Carbon monooxide-molybdenum (6:1) |
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| CAS号 | 13939-06-5 | 分子量 | 264.001 | |
| 密度 | 1.96 g/mL at 25 °C(lit.) | 沸点 | 156 °C(lit.) | |
| 分子式 | C6MoO6 | 熔点 | 150 °C (dec.)(lit.) | |
| MSDS | 中文版 美版 | 闪点 | N/A | |
| 符号 |
GHS06 |
信号词 | Danger |
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Determination of Ni(CO)4, Fe(CO)5, Mo(CO)6, and W(CO)6 in sewage gas by using cryotrapping gas chromatography inductively coupled plasma mass spectrometry.
J. Environ. Monit. 1(1) , 33-7, (1999) Evidence for the occurrence of Ni(CO)4 in addition to Mo(CO)6 and W(CO)6 in fermentation gases from a municipal sewage treatment plant is presented for the first time. The gases were sampled at the top of the sewage sludge digester using Tedlar bags, and were... |
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In situ generation of carbon monoxide from solid molybdenum hexacarbonyl. A convenient and fast route to palladium-catalyzed carbonylation reactions.
J. Comb. Chem. 4(2) , 109-11, (2002)
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Microwave-promoted aminocarbonylations of aryl chlorides using Mo(CO)(6) as a solid carbon monoxide source.
J. Comb. Chem. 8(1) , 4-6, (2006)
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Aminocarbonylations employing Mo(CO)6 and a bridged two-vial system: allowing the use of nitro group substituted aryl iodides and aryl bromides.
J. Org. Chem. 77(24) , 11393-8, (2012) A bridged two-vial system aminocarbonylation protocol where Mo(CO)(6) functions as an external in situ solid source of CO has been developed. For the first time both nitro group containing aryl/heteroaryl iodides and bromides gave good to excellent yields in ... |
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Enhanced photolysis in aerosols: evidence for important surface effects.
Phys. Chem. Chem. Phys. 8(40) , 4700-10, (2006) While there is increasing evidence for unique chemical reactions at interfaces, there are fewer data on photochemistry at liquid-vapor junctions. This paper reports a comparison of the photolysis of molybdenum hexacarbonyl, Mo(CO)(6), in 1-decene either as li... |
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Research spotlight: Microwave chemistry enabling the synthesis of biologically relevant amines.
Future Med. Chem. 2(2) , 161-8, (2010) Microwave-mediated chemistry, involving the reduction of nitroarenes with molybdenum hexacarbonyl as a stoichiometric reducing agent, has been employed in the synthesis of a range of anilines. Many of these reactions exhibit high levels of chemoselectivity, t... |
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Theoretical studies on the Mo-catalyzed asymmetric intramolecular Pauson-Khand-type [2+2+1] cycloadditions of 3-allyloxy-1-propynylphosphonates.
J. Mol. Model. 18(8) , 3489-99, (2012) Density functional theory (DFT) was used to investigate the Mo-catalyzed intramolecular Pauson-Khand reaction of 3-allyloxy-1-propynylphosphonates. All intermediates and transition states were optimized completely at the B3LYP/6-31 G(d,p) level [LANL2DZ(f) fo... |
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Adv. Synth. Catal. 352(10) , 1759-1769, (2010)
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Epoxidation of DL-limonene using an indenyl molybdenum(II) tricarbonyl complex as catalyst precursor Abrantes M, et al
Catal. Commun. 15(1) , 64-67, (2011)
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Selective adsorption of dibenzothiophene by functionalized metal organic frameworks sorbents Shi F, et al
Appl. Catal. B. 103(3-4) , 261-265, (2011)
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