1-(溴乙酰)芘
1-(溴乙酰)芘结构式
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常用名 | 1-(溴乙酰)芘 | 英文名 | 2-Bromo-1-(1-pyrenyl)ethanone |
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| CAS号 | 80480-15-5 | 分子量 | 323.183 | |
| 密度 | 1.6±0.1 g/cm3 | 沸点 | 476.7±18.0 °C at 760 mmHg | |
| 分子式 | C18H11BrO | 熔点 | 129-131ºC(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 109.3±8.5 °C | |
| 符号 |
GHS05 |
信号词 | Danger |
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Li⁺ selective podand-type fluoroionophore based on a diphenyl sulfoxide derivative bearing two pyrene groups.
Molecules 16(8) , 6844-57, (2011) New podand-type fluoroionophores having two pyrene moieties: 2,2´-bis(1-pyrenylacetyloxy)diphenyl sulfide (3), 2,2´-bis(1-pyrenylacetyloxy)diphenyl sulfoxide (4), and 2,2´-bis(1-pyrenylacetyloxy)diphenyl sulfone (5), have been synthesized by connecting two 1-... |
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Probing solution behaviour of metallosupramolecular complexes using pyrene fluorescence.
Dalton Trans. 41(5) , 1568-73, (2012) A new method for assessing the topology of metallosupramolecular assemblies using pyrene-appended ligands is reported. Two potentially tetradentate ligands containing one (L(1)) and two (L(2)) terminal pyrene moieties were synthesised and their complexes with... |
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In vitro bio-immunological and cytotoxicity studies of poly(2-oxazolines).
J. Mater. Sci. Mater. Med. 22(7) , 1725-34, (2011) Poly(2-oxazolines) with varying alkyl chain lengths (e.g., methyl, ethyl, aryl) and molar masses have been tested for cell cytotoxicity in vitro. A standard 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide (MTT) assay was used for the estimation o... |
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Basis for a new procedure to eliminate diarrheic shellfish toxins from a contaminated matrix.
J. Agric. Food Chem. 50(2) , 400-5, (2002) The natural contamination of shellfish with diarrheic shellfish toxins (DSP) has important public health implications. To avoid the economic effects of toxic episodes on shellfish farmers and the related industry, research on artificial methods alternative to... |
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Determination of dialkyl phosphates as breakdown products of organophosphorus insecticides in fruit juices by HPTLC with fluorescence detection.
J. AOAC Int. 92(3) , 691-8, (2009) Dialkyl phosphates (DAP) are common degradation products of organophosphorus pesticides that are used as urinary biomarkers for human exposure. An HPTLC method was developed for the quantitative determination of DAP in fruit juices, i.e., dimethyl phosphate (... |
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Determination of simvastatin and its active metabolite in human plasma by column-switching high-performance liquid chromatography with fluorescence detection after derivatization with 1-bromoacetylpyrene.
J. Chromatogr. B. Biomed. Sci. Appl. 694(1) , 211-7, (1997) By using a fluorescent derivatization and column-switching technique, a highly sensitive and selective high-performance liquid chromatographic (HPLC) method has been developed for the determination of simvastatin (I, beta-hydroxy-delta-lactone form) and its a... |
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Fluorescence high-performance liquid chromatographic determination of free and conjugated bile acids in serum and bile using 1-bromoacetylpyrene as a pre-labeling reagent.
J. Chromatogr. A. 272(1) , 29-41, (1983) A fluorescence high-performance liquid chromatographic method is described for the determination of free and conjugated bile acids in serum and bile. Free and conjugated bile acids are extracted from serum or bile using a Sep-Pak C18 cartridge and then fracti... |
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Isolation of dinophysistoxin-2 and the high-performance liquid chromatographic analysis of diarrhetic shellfish toxins using derivatisation with 1-bromoacetylpyrene.
J. Chromatogr. A. 749(1-2) , 33-40, (1996) The rare diarrhetic shellfish toxin, dinophysistoxin-2 (DTX-2), was isolated from the digestive glands of mussels (Mytilus edulis). This was achieved by chromatography on silica and Sephadex LH-20 followed by reversed-phase solid phase extraction and semi-pre... |
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Improvement on sample clean-up for high-performance liquid chromatographic-fluorimetric determination of diarrhetic shellfish toxins using 1-bromoacetylpyrene.
J. Chromatogr. A. 793(1) , 63-70, (1998) Okadaic acid (OA) and dinophysistoxin-2, two of the main diarrhetic shellfish toxins, can be determined by high-performance liquid chromatography coupled to fluorimetry as pyrenacyl esters. Toxin fluorescent derivatives were obtained after quantitative deriva... |
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1-Acetylpyrene with dual functions as an environment-sensitive fluorophore and fluorescent photoremovable protecting group. Jana A, et al.
Tetrahedron 66(52) , 9798-9807, (2010)
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