叔丁基异氰酸酯
一般危化品
叔丁基异氰酸酯结构式
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常用名 | 叔丁基异氰酸酯 | 英文名 | tert-Butylisocyanate |
|---|---|---|---|---|
| CAS号 | 1609-86-5 | 分子量 | 99.13110 | |
| 密度 | 0.868 g/mL at 25 °C(lit.) | 沸点 | 85-86 °C(lit.) | |
| 分子式 | C5H9NO | 熔点 | <-25ºC | |
| MSDS | 中文版 美版 | 闪点 | 24 °F | |
| 符号 |
GHS02, GHS05, GHS06, GHS08 |
信号词 | Danger |
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Synthesis and structural characterization of a terminal hydroxide containing alumoxane via hydrolysis of aluminum hydrides.
Inorg. Chem. 43(4) , 1217-9, (2004) A novel terminal hydroxide containing dinuclear alumoxane LAl(OH)OAlL(OCH=N-tBu) (3; L = HC(CMeNAr)2, Ar = 2,6-iPr2C6H3) was prepared by treatment of aluminum dihydride LAlH2 (1) and tert-butyl isocyanate in the presence of trace amounts of water and alternat... |
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Molybdenum oxo-imido aryloxide complexes: oxo analogues of olefin metathesis catalysts.
Inorg. Chem. 45(11) , 4556-61, (2006) The novel 16-electron molybdenum oxo-imido bis(aryloxide) complexes [Mo(NtBu)(O)(2,6-Me2C6H3O)2(py)] (1) and [Mo(NtBu)(O)(2,6-iPr2C6H3O)2(py)] (2) have been prepared by the salt elimination reactions of [Mo(NtBu)(O)Cl2(DME)] with the appropriate lithium arylo... |
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Versatile stereoselective cycloadditions between heterocumulenes and phosphagermaallene Tip(tBu)Ge=C=PMes*: experimental and theoretical investigations.
Chemistry 17(45) , 12763-72, (2011) Phosphagermaallene Tip(tBu)Ge=C=PMes* 1 (Tip=2,4,6-triisopropylphenyl, Mes*=2,4,6-tri-tert-butylphenyl) reacts with phenyl isocyanate and tert-butyl isocyanate by a [2+2] cycloaddition that involves the Ge=C and C=O double bonds to afford 1-oxa-2-germacyclobu... |
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Inhibition of carcinogen-induced neoplasia by sodium cyanate, tert-butyl isocyanate, and benzyl isothiocyanate administered subsequent to carcinogen exposure.
Cancer Res. 41(8) , 2991-4, (1981) The effects of sodium cyanate, tert-butyl isocyanate, and benzyl isothiocyanate on carcinogen-induced neoplasia were studied in experiments in which the test compound was fed starting 1 week following completion of carcinogen administrations. Under these cond... |