1,3-二氨基丙烷二盐酸盐 (低含水量)
1,3-二氨基丙烷二盐酸盐 (低含水量)结构式
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常用名 | 1,3-二氨基丙烷二盐酸盐 (低含水量) | 英文名 | 1,3-Propanediamine dihydrochloride |
|---|---|---|---|---|
| CAS号 | 10517-44-9 | 分子量 | 147.047 | |
| 密度 | 0.867g/cm3 | 沸点 | 135.5ºC at 760mmHg | |
| 分子式 | C3H12Cl2N2 | 熔点 | 246-250 °C(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 48.9ºC | |
| 符号 |
GHS06 |
信号词 | Danger |
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Metabolic engineering of Escherichia coli for the production of 1,3-diaminopropane, a three carbon diamine.
Sci. Rep. 5 , 13040, (2015) Bio-based production of chemicals from renewable resources is becoming increasingly important for sustainable chemical industry. In this study, Escherichia coli was metabolically engineered to produce 1,3-diaminopropane (1,3-DAP), a monomer for engineering pl... |
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The inducers 1,3-diaminopropane and spermidine produce a drastic increase in the expression of the penicillin biosynthetic genes for prolonged time, mediated by the laeA regulator.
Fungal Genet. Biol. 49(12) , 1004-13, (2012) We described previously that an autoinducer molecule, identified as 1,3-diaminopropane (1,3-DAP), is secreted by Penicillium chrysogenum and Acremonium chrysogenum. Using pH-controlled fermentor cultures we have observed in this work that 1,3-DAP and spermidi... |
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New tetradentate Schiff bases of 2,2-dimethyl-1,3-diaminopropane and acetylacetone derivatives and their vanadyl complexes.
Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 97 , 711-6, (2012) A series of new VO(IV) complexes with two new tetradentate Schiff base of 4,4'-(2,2-dimethylpropane-1,3-diyl)-bis(azan-1-yl-1-yldene)dipent-2-en-2-ol) [H(2)L(1)] and 3,3'-(2,2-dimethylpropane-1,3-diyl)azan-1-yl-1-ylidene)-bis(1-phenylbut-1-en-1-ol) [H(2)L(2)]... |
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Analysis of achromobactin biosynthesis by Pseudomonas syringae pv. syringae B728a.
J. Bacteriol. 191(14) , 4594-604, (2009) Pseudomonas syringae pv. syringae B728a is known to produce the siderophore pyoverdine under iron-limited conditions. It has also been proposed that this pathovar has the ability to produce a second siderophore, achromobactin. Here we present genetic and bioc... |
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Trans/cis isomerization of [RuCl2(diphosphine)(diamine)] complexes: synthesis, X-ray structure and catalytic activity in hydrogenation.
Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 105 , 466-73, (2013) The diamine (N-N) co-ligand 2,2-dimethyl-1,3-propanediamine and 2,3-diaminophathalene react individually with [RuCl(2)(dppb)(2)(μ-dppb)] to afford complexes with kinetically stable trans-[Cl(2)Ru(dppb)(N-N)] as the favoured isomer. The thermodynamically stabl... |
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Spectroscopic investigations of new binuclear transition metal complexes of Schiff bases derived from 4,6-diacetylresorcinol and 3-amino-1-propanol or 1,3-diamino-propane.
Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 68(3) , 592-604, (2007) The bifunctional carbonyl compound; 4,6-diacetylresorcinol (DAR) serves as precursor for the formation of different Schiff base ligands, which are either di- or tetra-basic with two symmetrical sets of either O2N or N2O tridentate chelating sites. The condens... |
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Synthesis, characterization and cytotoxicity of platinum(II)/palladium(II) complexes with 1,3-diaminopropane and 4-toluensulfonyl-L-amino acid dianion.
Eur. J. Med. Chem. 58 , 281-6, (2012) Eight novel platinum(II)/palladium(II) complexes with 1,3-dap and 4-toluensulfonyl-l-amino acid dianion, [Pt(1,3-dap)(TsalaNO)]·0.5H(2)O (1a), [Pt(1,3-dap)(TsvalNO)] (1b), [Pt(1,3-dap)(TspheNO)] (1c), [Pt(1,3-dap)(TsserNO)] (1d), [Pd(1,3-dap)(TsalaNO)]·1.5H(2... |
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Experimental study on vasoactive intestinal peptide (VIP) and its diaminopropane bound (VIP-DAP) analog in solution.
Amino Acids 35(2) , 275-81, (2008) Bioactive peptides represent an exciting area of research in the fields of biochemistry and medicine and in particular the VIP/PACAP network appears to be of interest. Vasoactive intestinal peptide (VIP) is a pleiotropic factor that exerts a physiological reg... |
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NMR studies of the stability, protonation States, and tautomerism of (13)C- AND (15)N-labeled aldimines of the coenzyme pyridoxal 5'-phosphate in water.
Biochemistry 49(51) , 10818-30, (2010) We have measured the pH-dependent (1)H, (13)C, and (15)N NMR spectra of pyridoxal 5'-phosphate ((13)C(2)-PLP) mixed with equal amounts of either doubly (15)N-labeled diaminopropane, (15)N(α)-labeled l-lysine, or (15)N(ε)-labeled l-lysine as model systems for ... |
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C-acylations of polymeric phosphoranylidene acetates for C-terminal variation of peptide carboxylic acids.
Org. Lett. 9(6) , 949-52, (2007) C-Acylations of polymer-supported 2-phosphoranylidene acetates ("linker reagents") with protected amino acids yielded 2-acyl-2-phosphoranylidene acetates as flexible intermediates for the C-terminal variation of carboxylic acids: peptidyl-2,3-diketoesters, pe... |