2-二环己基磷-2,4,6-三异丙基联苯
2-二环己基磷-2,4,6-三异丙基联苯结构式
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常用名 | 2-二环己基磷-2,4,6-三异丙基联苯 | 英文名 | X-Phos |
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| CAS号 | 564483-18-7 | 分子量 | 476.716 | |
| 密度 | N/A | 沸点 | 569.8±50.0 °C at 760 mmHg | |
| 分子式 | C33H49P | 熔点 | 187-190 °C(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 317.7±36.4 °C | |
| 符号 |
GHS08 |
信号词 | Warning |
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Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions employing dialkylbiaryl phosphine ligands.
Acc. Chem. Res. 41 , 1461, (2008) The cores of many types of polymers, ligands, natural products, and pharmaceuticals contain biaryl or substituted aromatic structures, and efficient methods of synthesizing these structures are crucial to the work of a broad spectrum of organic chemists. Rece... |
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Biaryl phosphane ligands in palladium-catalyzed amination.
Angew. Chem. Int. Ed. Engl. 47 , 6338, (2008) Palladium-catalyzed amination reactions of aryl halides have undergone rapid development in the last 12 years, largely driven by the implementation of new classes of ligands. Biaryl phosphanes have proven to provide especially active catalysts in this context... |
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Dialkylbiaryl Phosphines in Pd-Catalyzed Amination: A User's Guide.
Chem. Sci. 2 , 27, (2011) Dialkylbiaryl phosphines are a valuable class of ligand for Pd-catalyzed amination reactions and have been applied in a range of contexts. This review attempts to aid the reader in the selection of the best choice of reaction conditions and ligand of this cla... |
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Palladium-catalyzed borylation of aryl chlorides: scope, applications, and computational studies.
Angew. Chem. Int. Ed. Engl. 46 , 5359, (2007)
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Palladium-catalyzed, modular synthesis of highly functionalized indoles and tryptophans by direct annulation of substituted o-haloanilines and aldehydes.
J. Org. Chem. 71 , 7826, (2006) One-pot synthesis of indoles by a palladium-catalyzed annulation of ortho-haloanilines and aldehydes has been developed. Coupling of ortho-iodoaniline with aldehyde is realized under mild ligandless conditions [Pd(OAc)2, DABCO, DMF, 85 degrees C], whereas X-P... |
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Synthesis of C-15 vindoline analogues by palladium-catalyzed cross-coupling reactions.
J. Org. Chem. 71 , 7899, (2006) Described are general protocols for the rapid construction of various C-15-substituted analogues of vindoline using palladium-catalyzed cross-coupling reactions. The required bromo- and iodovindolines were prepared in high yield by the reaction of vindoline w... |
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Suzuki-Miyaura coupling of NHC-boranes: a new addition to the C-C coupling toolbox.
Org. Lett. 11 , 4914, (2009) Complexes of triaryl- and trialkylboranes with N-heterocyclic carbenes (NHCs) participate in Suzuki-Miyaura cross-coupling reactions and provide coupled products in good yields under base-free conditions. The reaction can be applied to Csp(2)-Csp(2) and Csp(2... |
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Tetrahedron Lett. 47 , 5143, (2006)
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