三苯基膦醋酸钯
三苯基膦醋酸钯结构式
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常用名 | 三苯基膦醋酸钯 | 英文名 | Diacetatobis(triphenylphosphine) palladium(II) |
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| CAS号 | 14588-08-0 | 分子量 | 749.079 | |
| 密度 | N/A | 沸点 | 360ºC at 760 mmHg | |
| 分子式 | C40H36O4P2Pd | 熔点 | 136ºC | |
| MSDS | 中文版 美版 | 闪点 | 181.7ºC |
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Palladium(II) Acetate-Tris(triphenylphosphine)rhodium(I) Chloride: A Novel Catalytic Couple for the Intramolecular Heck Reaction.
J. Org. Chem. 64 , 3461, (1999) A series of crotyl ethers underwent intramolecular cyclizations in the presence of a novel catalytic couple, composed of tris(triphenylphosphine)rhodium(I) chloride and palladium(II) acetate, under Heck conditions initially described by Jeffery.(1) The data i... |
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Formal total synthesis of oximidine II via a Suzuki-type cross-coupling macrocyclization employing potassium organotrifluoroborates.
J. Am. Chem. Soc. 126 , 10313, (2004) A formal total synthesis of oximidine II has been achieved, employing a Suzuki-type coupling approach to construct the highly strained, polyunsaturated 12-membered macrolactone. To achieve this goal, benefit was derived from the stability of potassium alkenyl... |
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Yus, M.; Gomis, J.
Tetrahedron Lett. 42 , 5721, (2001)
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Jang, M.-Y.; De Jonghe, S.; et al.
Tetrahedron Lett. 47 , 8917, (2006)
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