1-[(三异丙基硅烷基)乙炔基]-1,2-苯碘酰-3(1H)-酮
![1-[(三异丙基硅烷基)乙炔基]-1,2-苯碘酰-3(1H)-酮结构式](https://image.chemsrc.com/caspic/442/181934-30-5.png)
1-[(三异丙基硅烷基)乙炔基]-1,2-苯碘酰-3(1H)-酮结构式
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常用名 | 1-[(三异丙基硅烷基)乙炔基]-1,2-苯碘酰-3(1H)-酮 | 英文名 | 1-[(Triisopropylsilyl)ethynyl]-1,2-benziodoxol-3(1H)-one |
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| CAS号 | 181934-30-5 | 分子量 | 428.380 | |
| 密度 | N/A | 沸点 | N/A | |
| 分子式 | C18H25IO2Si | 熔点 | 170 °C(dec.) | |
| MSDS | 中文版 美版 | 闪点 | N/A | |
| 符号 |
GHS07 |
信号词 | Warning |
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Pd-catalyzed intramolecular oxyalkynylation of alkenes with hypervalent iodine.
Org. Lett. 12 , 384-387, (2010) The first example of intramolecular oxyalkynylation of nonactivated alkenes using oxidative Pd chemistry is reported. Both phenol and aromatic or aliphatic acid derivatives could be used under operator-friendly conditions (room temperature, technical solvents... |
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Direct alkynylation of indole and pyrrole heterocycles.
Angew. Chem. Int. Ed. Engl. 48 , 9346-9349, (2009)
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