2,6-二叔丁基-4-甲基吡啶
2,6-二叔丁基-4-甲基吡啶结构式
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常用名 | 2,6-二叔丁基-4-甲基吡啶 | 英文名 | 2,6-Di-tert-butyl-4-methylpyridine |
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| CAS号 | 38222-83-2 | 分子量 | 205.34 | |
| 密度 | 0.9±0.1 g/cm3 | 沸点 | 233.0±0.0 °C at 760 mmHg | |
| 分子式 | C14H23N | 熔点 | 33-36 °C(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 83.9±0.0 °C | |
| 符号 |
GHS07 |
信号词 | Warning |
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Cyclization reactions of homopropargyl azide derivatives catalyzed by PtCl4 in ethanol solution: synthesis of functionalized pyrrole derivatives.
Org. Lett. 8(23) , 5349-52, (2006) [Structure: see text] PtCl4-catalyzed cyclization reactions of homopropargyl azide derivatives to pyrrole rings were investigated. Using ethanol as solvent with 2,6-di-tert-butyl-4-methylpyridine as the base was found to be the best set of conditions for effe... |
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GaCl(3)-catalyzed ortho-ethynylation of phenols.
J. Am. Chem. Soc. 124(29) , 8528-9, (2002) Phenols are ethynylated at the ortho position with silylated chloroethyne in the presence of a catalytic amount of GaCl3 and lithium phenoxide. The lithium salt is essential for the catalysis, and addition of 2,6-di(tert-butyl)-4-methylpyridine inhibits desil... |
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2-Methoxybenzoyl phosphate: a new substrate for continuous fluorimetric and spectrophotometric acyl phosphatase assays.
J. Org. Chem. 65(3) , 801-5, (2000) A new aromatic acyl phosphate, 2-methoxybenzoyl phosphate, has been synthesized. The compound shows an intrinsic fluorescence; it displays an intense emission band at 390 nm upon excitation in the near UV region. This band practically disappears after hydroly... |
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Silylium ion-promoted dehydrogenative cyclization: synthesis of silicon-containing compounds derived from alkynes.
Chem. Commun. (Camb.) , (2014) Treatment of dialkylbenzylsilane (1) with trityl tetrakis(pentafluorophenyl)borate (TPFPB) in the presence of terminal or internal alkynes (3) and 2,6-di-tert-butyl-4-methylpyridine gave the corresponding 1,2-dihydro-2-silanaphthalene derivatives (4) in 34-82... |
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Synthesis , 283, (1980)
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Organic Synth. 68 , 138, (1990)
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