叔丁基氰基二甲基硅烷
叔丁基氰基二甲基硅烷结构式
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常用名 | 叔丁基氰基二甲基硅烷 | 英文名 | Dimethyl(2-methyl-2-propanyl)silanecarbonitrile |
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| CAS号 | 56522-24-8 | 分子量 | 141.286 | |
| 密度 | 0.8±0.1 g/cm3 | 沸点 | 166.4±9.0 °C at 760 mmHg | |
| 分子式 | C7H15NSi | 熔点 | 76-79ºC(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 54.5±18.7 °C | |
| 符号 |
GHS06 |
信号词 | Danger |
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Stereocontrolled access to orthogonally protected anti,anti-4-aminopiperidine-3,5-diols through chemoselective reduction of enantiopure beta-lactam cyanohydrins.
J. Org. Chem. 72(21) , 7980-91, (2007) The cyanosilylation of enantiopure 4-oxoazetidine-2-carbaldehydes with tert-butyldimethylsilyl cyanide was promoted by either molecular sieves or catalytic amount of sodium carbonate to give O-silylated beta-lactam cyanohydrins with good yield and diastereose... |
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J. Org. Chem. 51 , 5010, (1986)
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Addition of tert-butyldimethyl-or tert-butyldiphenylsilyl cyanide to hindered ketones. Golinski M, et al.
J. Org. Chem. 58(1) , 159-64, (1993)
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P(RNCH2CH2)N: efficient catalysts for the cyanosilylation of aldehydes and ketones. Fetterly BM and Verkade JG.
Tetrahedron Lett. 46(46) , 8061-66, (2005)
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