2-硝基-N'-(2-亚丙基)-苯磺酰肼
2-硝基-N'-(2-亚丙基)-苯磺酰肼结构式
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常用名 | 2-硝基-N'-(2-亚丙基)-苯磺酰肼 | 英文名 | N'-Isopropylidene-2-nitrobenzenesulfonohydrazide |
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| CAS号 | 6655-27-2 | 分子量 | 257.266 | |
| 密度 | 1.4±0.1 g/cm3 | 沸点 | 421.3±47.0 °C at 760 mmHg | |
| 分子式 | C9H11N3O4S | 熔点 | 131-135ºC | |
| MSDS | 美版 | 闪点 | 208.6±29.3 °C |
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N-isopropylidene-N'-2-nitrobenzenesulfonyl hydrazine, a reagent for reduction of alcohols via the corresponding monoalkyl diazenes.
J. Org. Chem. 72 , 1838, (2007) The reagent N-isopropylidene-N'-2-nitrobenzenesulfonyl hydrazine (IPNBSH) is used in the reduction of alcohols via the loss of dinitrogen from transiently formed monoalkyl diazene intermediates accessed by sequential Mitsunobu displacement, hydrolysis, and fr... |
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A stereospecific palladium-catalyzed route to monoalkyl diazenes for mild allylic reduction.
Angew. Chem. Int. Ed. Engl. 47 , 8909, (2008)
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