N'-Isopropylidene-2-nitrobenzenesulfonohydrazide
N'-Isopropylidene-2-nitrobenzenesulfonohydrazide structure
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Common Name | N'-Isopropylidene-2-nitrobenzenesulfonohydrazide | ||
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| CAS Number | 6655-27-2 | Molecular Weight | 257.266 | |
| Density | 1.4±0.1 g/cm3 | Boiling Point | 421.3±47.0 °C at 760 mmHg | |
| Molecular Formula | C9H11N3O4S | Melting Point | 131-135ºC | |
| MSDS | USA | Flash Point | 208.6±29.3 °C | |
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N-isopropylidene-N'-2-nitrobenzenesulfonyl hydrazine, a reagent for reduction of alcohols via the corresponding monoalkyl diazenes.
J. Org. Chem. 72 , 1838, (2007) The reagent N-isopropylidene-N'-2-nitrobenzenesulfonyl hydrazine (IPNBSH) is used in the reduction of alcohols via the loss of dinitrogen from transiently formed monoalkyl diazene intermediates accessed by sequential Mitsunobu displacement, hydrolysis, and fr... |
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A stereospecific palladium-catalyzed route to monoalkyl diazenes for mild allylic reduction.
Angew. Chem. Int. Ed. Engl. 47 , 8909, (2008)
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