二氟溴乙酸乙酯
二氟溴乙酸乙酯结构式
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常用名 | 二氟溴乙酸乙酯 | 英文名 | ethylbrom(difluor)acetat |
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| CAS号 | 667-27-6 | 分子量 | 202.982 | |
| 密度 | 1.7±0.1 g/cm3 | 沸点 | 114.7±35.0 °C at 760 mmHg | |
| 分子式 | C4H5BrF2O2 | 熔点 | N/A | |
| MSDS | 中文版 美版 | 闪点 | 23.2±25.9 °C | |
| 符号 |
GHS02, GHS05 |
信号词 | Danger |
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Synthesis of 4-substituted 3,3-difluoropiperidines.
J. Org. Chem. 75(3) , 929-32, (2010) Synthetic strategies toward 4-substituted 3,3-difluoropiperidines were evaluated. 4-Alkoxymethyl- and 4-aryloxymethyl-3,3-difluoropiperidines were synthesized via 1,4-addition of ethyl bromodifluoroacetate to 3-substituted acrylonitriles in the presence of co... |
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Visible-light-mediated fluoroalkylation of isocyanides with ethyl bromofluoroacetates: unified synthesis of mono- and difluoromethylated phenanthridine derivatives.
Org. Lett. 16(11) , 2938-41, (2014) A practical and unified strategy has been described for the preparation of mono- and difluoromethylated phenanthridine derivatives using a visible-light-promoted alkylation and decarboxylation sequence from biphenyl isocyanides with ethyl bromofluoroacetate (... |
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Enantioselective synthesis of α,α-difluoro-β-lactams using amino alcohol ligands.
Org. Biomol. Chem. 12(33) , 6484-9, (2014) A practical and highly enantioselective Reformatsky reaction of ethyl bromodifluoroacetate with imines using a cheap and commercially available amino alcohol ligand is described. A variety of α,α-difluoro-β-lactams were obtained in up to 74% yield with high e... |
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Copper-mediated reaction of 2-halopyridines with ethyl bromodifluoroacetate. Ashwood MS, et al.
Tetrahedron Lett. 43(50) , 9271-73, (2002)
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