对甲基苯磺酰甲基异腈
对甲基苯磺酰甲基异腈结构式
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常用名 | 对甲基苯磺酰甲基异腈 | 英文名 | Tosylmethyl isocyanide |
|---|---|---|---|---|
| CAS号 | 36635-61-7 | 分子量 | 195.238 | |
| 密度 | 1.24 g/cm3 | 沸点 | 400.9ºC at 760 mmHg | |
| 分子式 | C9H9NO2S | 熔点 | 109-113 °C(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 196.3ºC | |
| 符号 |
GHS06 |
信号词 | Danger |
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Microwave-assisted synthesis of imidazoles: reaction of p-toluenesulfonylmethyl isocyanide and polymer-bound imines.
Bioorg. Med. Chem. Lett. 15(16) , 3717-9, (2005) A convenient method for the synthesis of 1,5-disubstituted imidazoles has been developed on a polymeric support using base-promoted 1,3-dipolar cycloaddition reaction of p-toluenesulfonylmethyl isocyanide (TOSMIC) with immobilized imines under microwave irrad... |
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Synthesis of novel triplet drugs with 1,3,5-trioxazatriquinane skeletons and their pharmacologies. Part 2: Synthesis of novel triplet drugs with the epoxymethano structure (capped homotriplet).
Bioorg. Med. Chem. Lett. 21(20) , 6198-202, (2011) An improved synthetic method for triplet drugs with the 1,3,5-trioxazatriquinane skeleton was developed that used p-toluenesulfonylmethyl isocyanide (TosMIC) instead of 1,3-dithiane. Using the improved method, we synthesized compounds with two identical pharm... |
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Alkyl and aromatic isocyanide binding to haem complexes.
Biochem. J. 262(3) , 959-63, (1989) Equilibrium constants for the binding of ethyl (EIC), n-butyl (BIC), p-toluenesulphonylmethyl (TMIC) and 2,6-dimethylphenyl isocyanides (DIMPI) to an imidazole-haem complex in toluene and aqueous detergent micelle solutions were determined. In contrast to an ... |
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Med. Chem. Res. 3 , 192, (1993)
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Il Farmaco 48 , 209, (1993)
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Tetrahedron Lett. 48 , 5977, (2006)
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p-Toluenesulfonylmethyl Isocyanide: A Versatile Synthon in Organic Chemistry. Tandon VK and Rai S.
J. Sulfur Chem. 24(3) , 307-85, (2003)
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