苯硫酚钠
苯硫酚钠结构式
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常用名 | 苯硫酚钠 | 英文名 | Sodium benzenethiolate |
|---|---|---|---|---|
| CAS号 | 930-69-8 | 分子量 | 132.159 | |
| 密度 | 1.079g/cm3 | 沸点 | 169.1ºC at 760mmHg | |
| 分子式 | C6H5NaS | 熔点 | >300ºC | |
| MSDS | 中文版 美版 | 闪点 | 50.6ºC | |
| 符号 |
GHS05 |
信号词 | Danger |
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Hybrid plasmonic platforms based on silica-encapsulated gold nanorods as effective spectroscopic enhancers for Raman and fluorescence spectroscopy.
Nanotechnology 23(48) , 485706, (2012) Surface-enhanced Raman scattering (SERS) nano-tags are of increasing interest in biomedical research as viable alternatives to bio-imaging techniques based on semiconductor quantum dots or fluorescent molecules. In this work, we fabricate silica-coated gold n... |
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A highly active and magnetically retrievable nanoferrite-DOPA-copper catalyst for the coupling of thiophenols with aryl halides.
Chem. Commun. (Camb.) 48(20) , 2582-4, (2012) Diaryl sulfides were synthesized using a magnetically recoverable heterogeneous Cu catalyst via one-pot multi component reaction using MW irradiation; the use of isopropanol as a benign reaction medium, easy recovery of the catalyst using an external magnet, ... |
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Electrochemical, high-resolution photoemission spectroscopy and vdW-DFT study of the thermal stability of benzenethiol and benzeneselenol monolayers on Au(111).
Langmuir 28(38) , 13624-35, (2012) The preparation and thermal stability of benzenethiol and benzeneselenol self-assembled monolayers (SAMs) grown on Au(111) have been investigated by electrochemical experiments and high-resolution photoemission spectroscopy. Both techniques confirm the format... |
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Synthesis of phenothiazines via ligand-free CuI-catalyzed cascade C-S and C-N coupling of aryl ortho-dihalides and ortho-aminobenzenethiols.
Chem. Commun. (Camb.) 48(43) , 5367-9, (2012) A ligand-free CuI-catalyzed cascade C-S and C-N cross coupling of (hetero)aryl ortho-dihalides and ortho-aminobenzenethiols has been developed, and various phenothiazines were synthesized with excellent regioselectivity. A possible mechanism is proposed for t... |
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Acute toxicity and n-octanol/water partition coefficients of substituted thiophenols: determination and QSAR analysis.
Ecotoxicol. Environ. Saf. 78 , 134-41, (2012) The acute toxicity (-log EC(50)) to Photobacterium phosphoreum and the n-octanol/water partition coefficient (log K(ow)) of 31 kinds of substituted thiophenols were determined at 298.15K. The -log EC(50) values of studied chemicals are between 4.26 and 5.89. ... |
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Controlling electronic product branching at conical intersections in the UV photolysis of para-substituted thiophenols.
J. Phys. Chem. A 116(51) , 12444-59, (2012) H (Rydberg) atom photofragment translation spectroscopy and high-level ab initio electronic structure calculations are used to explore the photodissociation dynamics of three para-substituted thiophenols (p-YPhSH; Y = CH(3), F, and MeO). UV excitation in the ... |
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Non-enzymatic conversion of chlorophyll-a into chlorophyll-d in vitro: a model oxidation pathway for chlorophyll-d biosynthesis.
FEBS Lett. 586(16) , 2338-41, (2012) Chlorophyll-a (Chl-a) was readily converted into Chl-d under mild conditions without any enzymes. Treatment of Chl-a dissolved in dry tetrahydrofuran (THF) with thiophenol and acetic acid at room temperature successfully produced Chl-d in 31% yield. During th... |
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Solid-state synthesis of molybdenum and tungsten porphyrins and aerial oxidation of coordinated benzenethiolate to benzenesulfonate.
Inorg. Chem. 51(11) , 6412-20, (2012) A new route is developed for the synthesis of molybdenum and tungsten porphyrins using [M(NO)(2)py(2)Cl(2)] (M = Mo, W) as the metal source and TPP (dianion of 5,10,15,20-meso-tetraphenylporphyrin) in the benzoic acid melt. Complexes [Mo(V)O(TPP)(OOCPh)] (1) ... |
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4H-1,4-benzothiazine, dihydro-1,4-benzothiazinones and 2-amino-5-fluorobenzenethiol derivatives: design, synthesis and in vitro antimicrobial screening.
Arch. Pharm. (Weinheim) 345(5) , 407-16, (2012) As part of our studies focused on the design and synthesis of new antimicrobial agents a series of 7-fluoro-3,4-dihydro-2H-1,4-benzothiazine derivatives (4a-4f, 4h) and 7-fluoro-2H-1,4-benzothiazin-3(4H)-one analogues (4j-4o) were synthesized and evaluated fo... |
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Differentiating intrinsic SERS spectra from a mixture by sampling induced composition gradient and independent component analysis.
Analyst 137(1) , 73-6, (2012) By generating a composition gradient on a highly uniform SERS substrate and applying independent component analysis, we demonstrate that one can extract the intrinsic SERS spectrum of individual components from SERS spectra obtained from a two-component mixtu... |