烯丙基溴
一般危化品
烯丙基溴结构式
|
常用名 | 烯丙基溴 | 英文名 | allyl bromide |
|---|---|---|---|---|
| CAS号 | 106-95-6 | 分子量 | 120.976 | |
| 密度 | 1.4±0.1 g/cm3 | 沸点 | 68.1±9.0 °C at 760 mmHg | |
| 分子式 | C3H5Br | 熔点 | -119 °C | |
| MSDS | 中文版 美版 | 闪点 | -2.2±0.0 °C | |
| 符号 |
GHS02, GHS05, GHS06, GHS08, GHS09 |
信号词 | Danger |
|
Novel amphiphilic cationic porphyrin and its Ag(II) complex as potential anticancer agents.
J. Inorg. Biochem. 140 , 94-103, (2014) In the present study we have synthesized a novel amphiphilic porphyrin and its Ag(II) complex through modification of water-soluble porphyrinic structure in order to increase its lipophilicity and in turn pharmacological potency. New cationic non-symmetrical ... |
|
|
Molecular self assembly of mixed comb-like dextran surfactant polymers for SPR virus detection.
Carbohydr. Polym. 112 , 440-7, (2014) The synthesis of two comb-like dextran surfactant polymers, that are different in their dextran molecular weight (MW) distribution and the presence of carboxylic groups, and their characterization are reported. A bimodal carboxylic dextran surfactant polymer ... |
|
|
S-allylcysteine prevents cisplatin-induced nephrotoxicity and oxidative stress.
J. Pharm. Pharmacol. 66(9) , 1271-81, (2014) Cisplatin (CP) is an antineoplastic agent that induces nephrotoxicity and oxidative stress. S-allylcysteine (SAC) is a garlic-derived antioxidant. This study aims to explore whether SAC protects against CP-induced nephrotoxicity in rats.In the first stage, th... |
|
|
Bioconversion of ethyl 4-chloro-3-oxobutanoate by permeabilized fresh brewer's yeast cells in the presence of allyl bromide.
J. Ind. Microbiol. Biotechnol. 34(2) , 151-6, (2007) Ethyl(R)-4-chloro-3-hydroxybutanoate ((R)-CHBE) are obtained by cetyltrimetylammonium bromide (CTAB) permeabilized fresh brewer's yeast whole cells bioconversion of ethyl 4-chloro-3-oxobutanoate (COBE ) in the presence of allyl bromide. The results showed tha... |
|
|
Design and synthesis of modular oxazoline ligands for the enantioselective chromium-catalyzed addition of allyl bromide to ketones.
J. Am. Chem. Soc. 129(10) , 2752-3, (2007)
|
|
|
Reactivity and enantioselectivity in the reactions of scalemic stereogenic alpha-(N-carbamoyl)alkylcuprates.
J. Org. Chem. 69(9) , 3076-86, (2004) Stereogenic 2-(N-carbamoyl)pyrrolidinylcuprates prepared from scalemic (i.e., enantioenriched) N-Boc-2-lithiopyrrolidine and THF soluble CuCN.2LiCl react with vinyl iodides, vinyl triflates, beta-iodo-alpha,beta-enoates, propargyl mesylates, and allyl bromide... |
|
|
Silicones containing pendant biocides for antifouling coatings.
Biofouling 20(4-5) , 227-36, (2004) The preparation of biocide-incorporated silicone coatings for antifouling/fouling release applications is described. The biocide Triclosan (5-chloro-2-(2, 4-dichlorophenoxy) phenol) was modified with alkenyl moieties and incorporated into a silicone backbone ... |
|
|
An electrochemical coupling of organic halide with aldehydes, catalytic in chromium and nickel salts. the Nozaki-Hiyama-Kishi reaction.
Org. Lett. 3(13) , 2073-6, (2001) [reaction: see text] Electrochemical arylation of arenecarboxaldehydes using an iron sacrificial anode in the presence of chromium and nickel catalysts afforded the corresponding arylated secondary alcohols in moderate to good yields. The chromium and nickel ... |
|
|
Allylic compounds bind directly to DNA: investigation of the binding mechanisms in vitro.
Chem. Biol. Interact. 61(2) , 97-108, (1987) The in vitro binding of three allyl compounds, allyl methanesulphonate, allyl bromide and allyl chloride to DNA from salmon sperm was investigated. Kinetic DNA-alkylation measurements revealed significant differences between the strongly alkylating allyl meth... |
|
|
Reactivity of alkynylzirconates towards allyl bromides: selective formation of β-allyl-zirconacyclopentadienes.
Chem. Commun. (Camb.) 46(41) , 7801-3, (2010) Reaction of alkynylzirconates with allyl bromides afforded β-allyl-zirconacyclopentadienes with high selectivity in unique reaction site. |