[2-(二环己基膦)-3,6-二甲氧基-2',4',6'-三异丙基-1,1'-联苯]金(I)双(三氟甲磺酰基)亚胺结构式
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常用名 | [2-(二环己基膦)-3,6-二甲氧基-2',4',6'-三异丙基-1,1'-联苯]金(I)双(三氟甲磺酰基)亚胺 | 英文名 | BrettPhos AuNTf |
|---|---|---|---|---|
| CAS号 | 1296269-97-0 | 分子量 | 1013.88000 | |
| 密度 | N/A | 沸点 | N/A | |
| 分子式 | C37H53AuF6NO6PS2 | 熔点 | N/A | |
| MSDS | 中文版 美版 | 闪点 | N/A | |
| 符号 |
GHS07 |
信号词 | Warning |
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Gold-catalyzed cyclizations of cis-enediynes: insights into the nature of gold-aryne interactions.
Angew. Chem. Int. Ed. Engl. 52(30) , 7795-9, (2013) Golden aryne? Gold aryne complexes are inferred as transition states in dual gold-catalyzed cyclizations of cis-enediynes (see scheme; DCE = 1,2-dichloroethane). They are better described as ortho-aurophenyl cations, which react with weak nucleophiles and und... |
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