亚磷酸二甲酯
亚磷酸二甲酯结构式
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常用名 | 亚磷酸二甲酯 | 英文名 | Dimethyl phosphonate |
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| CAS号 | 868-85-9 | 分子量 | 110.049 | |
| 密度 | 1.2 g/mL at 25 °C(lit.) | 沸点 | 170.5±0.0 °C at 760 mmHg | |
| 分子式 | C2H7O3P | 熔点 | N/A | |
| MSDS | 中文版 美版 | 闪点 | 29.4±0.0 °C | |
| 符号 |
GHS07, GHS08 |
信号词 | Warning |
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Does phosphoryl protonation occurs in aqueous phosphoesters solutions.
Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 62(1-3) , 287-92, (2005) Ionisation of trimethylphosphate (TMP), dimethylphosphate (DMP) and diethylphosphate (DEP) is investigated by acidic titration in water by Raman (R), Fourier transform infrared (FTIR) and nuclear magnetic resonance (NMR) spectroscopies. The vibrational freque... |
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Dealkylation of phosphonate esters with chlorotrimethylsilane.
Nucleosides Nucleotides Nucleic Acids 20(4-7) , 1299-302, (2001) Chlorotrimethylsilane completely dealkylates phosphonate esters at elevated temperature in a sealed reaction vessel. These conditions are tolerated by a variety of functional groups and lead to high conversions of dimethyl, diethyl and diisopropyl phosphonate... |
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Multidimensional analytical method based on binary phase shaping of femtosecond pulses.
J. Phys. Chem. A 109(11) , 2413-6, (2005) Multidimensional chemical detection and identification based on phase shaped femtosecond laser pulses coupled to mass spectrometry is demonstrated. The method based on binary phase shaping (BPS) takes into account the accuracy and precision standards required... |
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Handling within run retention time shifts in two-dimensional chromatography data using shift correction and modeling.
J. Chromatogr. A. 1216(18) , 4020-9, (2009) The use of PARAFAC for modeling GC x GC-TOFMS peaks is well documented. This success is due to the trilinear structure of these data under ideal, or sufficiently close to ideal, chromatographic conditions. However, using temperature programming to cope with t... |
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[A new method of fixing histological preparations using dimethylphosphite].
Morfologiia. 106(4-6) , 169-70, (1994)
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Dimethyl hydrogen phosphite.
IARC Monogr. Eval. Carcinog. Risks Hum. 48 , 85-93, (1990)
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[Experimental data on the hygienic regulation of dimethyl phosphite in the air of a work area].
Gig. Tr. Prof. Zabol. (4) , 22-3, (1992) Dimethylphosphite, being a semiproduct of chlorophosphonium synthesis, is a moderately toxic substance according to the criterion of acute toxicity. It is characterized by marked cumulative properties, absorption from skin and local irritative action. Acute a... |
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Dimethyl hydrogen phosphite.
IARC Monogr. Eval. Carcinog. Risks Hum. 71 Pt 3 , 1437-40, (1999)
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Removal of glyphosate in neutralization liquor from the glycine-dimethylphosphit process by nanofiltration.
J. Hazard. Mater. 181(1-3) , 975-80, (2010) Nanofiltration (NF) was investigated for the removal of glyphosate in the neutralization liquor produced by the glycine-dimethylphosphit process. The Desal-5 DK membrane was chosen as the most suitable membrane for the NF process when compared to the DL and N... |
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Plasma chemical degradation of phosphorous-containing warfare agents simulants.
J. Hazard. Mater. 175(1-3) , 1037-41, (2010) The gliding electric discharge (or "glidarc") technique is a new advanced oxidation process used for the degradation of organic solutes or spent solvents. Discharges in humid air at atmospheric pressure produce active species (i.e., .OH and .NO) that are able... |