异丙烯基氧代三甲基硅烷
异丙烯基氧代三甲基硅烷结构式
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常用名 | 异丙烯基氧代三甲基硅烷 | 英文名 | (Isopropenyloxy)(trimethyl)silane |
|---|---|---|---|---|
| CAS号 | 1833-53-0 | 分子量 | 130.260 | |
| 密度 | 0.8±0.1 g/cm3 | 沸点 | 93.0±8.0 °C at 760 mmHg | |
| 分子式 | C6H14OSi | 熔点 | N/A | |
| MSDS | 中文版 美版 | 闪点 | 7.2±0.0 °C | |
| 符号 |
GHS02, GHS07 |
信号词 | Danger |
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Concise total synthesis and stereochemical revision of (+)-naseseazines A and B: regioselective arylative dimerization of diketopiperazine alkaloids.
J. Am. Chem. Soc. 133 , 14940-14943, (2011) Concise and enantioselective total syntheses of (+)-naseseazines A and B are described. Our regioselective and directed dimerization of diketopiperazines provides their critical C3-C(sp(2)) linkages, an assembly with plausible biogenetic relevance. We revise ... |
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Total synthesis of (+/-)-powelline and (+/-)-buphanidrine.
Org. Lett. 12(6) , 1252-4, (2010) The total synthesis of (+/-)-powelline (13 linear steps in an overall yield of 6%) and (+/-)-buphanidrine (14 linear steps and a 6% overall yield) and has been achieved using a novel approach to the crinane skeleton. An organocatalytic oxidative coupling allo... |
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Organotin triflate as practical catalyst for Michael addition of enol silyl ethers. Sato T, et al.
Tetrahedron 47(47) , 9773-82, (1991)
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