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丙二酸叔丁基甲酯

丙二酸叔丁基甲酯结构式
丙二酸叔丁基甲酯结构式
品牌特惠专场
常用名 丙二酸叔丁基甲酯 英文名 tert-Butyl methyl malonate
CAS号 42726-73-8 分子量 174.194
密度 1.0±0.1 g/cm3 沸点 197.7±0.0 °C at 760 mmHg
分子式 C8H14O4 熔点 -10ºC
MSDS 美版 闪点 79.4±0.0 °C

Stereospecific Pd(O)-catalyzed malonate additions to allylic hydroxy phosphonate derivatives: a formal synthesis of (-)-enterolactone.

J. Org. Chem. 69(8) , 2859-62, (2004)

A combination of cross-metathesis and malonate addition was applied to a formal synthesis of the mammalian lignan enterolactone 5. The cross-metathesis of alkene 6 and phosphonate 3a gave the substituted allylic phosphonate 3d. The palladium-catalyzed additio...