![]() 丙二酸叔丁基甲酯结构式
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常用名 | 丙二酸叔丁基甲酯 | 英文名 | tert-Butyl methyl malonate |
---|---|---|---|---|
CAS号 | 42726-73-8 | 分子量 | 174.194 | |
密度 | 1.0±0.1 g/cm3 | 沸点 | 197.7±0.0 °C at 760 mmHg | |
分子式 | C8H14O4 | 熔点 | -10ºC | |
MSDS | 美版 | 闪点 | 79.4±0.0 °C |
Stereospecific Pd(O)-catalyzed malonate additions to allylic hydroxy phosphonate derivatives: a formal synthesis of (-)-enterolactone.
J. Org. Chem. 69(8) , 2859-62, (2004) A combination of cross-metathesis and malonate addition was applied to a formal synthesis of the mammalian lignan enterolactone 5. The cross-metathesis of alkene 6 and phosphonate 3a gave the substituted allylic phosphonate 3d. The palladium-catalyzed additio... |
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