tert-Butyl methyl malonate
tert-Butyl methyl malonate structure
|
Common Name | tert-Butyl methyl malonate | ||
|---|---|---|---|---|
| CAS Number | 42726-73-8 | Molecular Weight | 174.194 | |
| Density | 1.0±0.1 g/cm3 | Boiling Point | 197.7±0.0 °C at 760 mmHg | |
| Molecular Formula | C8H14O4 | Melting Point | -10ºC | |
| MSDS | USA | Flash Point | 79.4±0.0 °C | |
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Stereospecific Pd(O)-catalyzed malonate additions to allylic hydroxy phosphonate derivatives: a formal synthesis of (-)-enterolactone.
J. Org. Chem. 69(8) , 2859-62, (2004) A combination of cross-metathesis and malonate addition was applied to a formal synthesis of the mammalian lignan enterolactone 5. The cross-metathesis of alkene 6 and phosphonate 3a gave the substituted allylic phosphonate 3d. The palladium-catalyzed additio... |
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