氟磺酰二氟乙酸甲酯
氟磺酰二氟乙酸甲酯结构式
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常用名 | 氟磺酰二氟乙酸甲酯 | 英文名 | Methyldifluor(fluorsulfonyl)acetat |
|---|---|---|---|---|
| CAS号 | 680-15-9 | 分子量 | 192.114 | |
| 密度 | 1.6±0.1 g/cm3 | 沸点 | 150.0±40.0 °C at 760 mmHg | |
| 分子式 | C3H3F3O4S | 熔点 | N/A | |
| MSDS | 中文版 美版 | 闪点 | 44.5±27.3 °C | |
| 符号 |
GHS02, GHS05 |
信号词 | Danger |
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Evaluating the thermal vinylcyclopropane rearrangement (VCPR) as a practical method for the synthesis of difluorinated cyclopentenes: experimental and computational studies of rearrangement stereospecificity.
Chemistry 20(44) , 14305-16, (2014) Vinyl cyclopropane rearrangement (VCPR) has been utilised to synthesise a difluorinated cyclopentene stereospecifically and under mild thermal conditions. Difluorocyclopropanation chemistry afforded ethyl 3-(1'(2'2'-difluoro-3'-phenyl)cyclopropyl) propenoate ... |
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A broadly applicable copper reagent for trifluoromethylations and perfluoroalkylations of aryl iodides and bromides.
Angew. Chem. Int. Ed. Engl. 50 , 3793, (2011)
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J. Chem. Soc. Chem. Commun. , 705, (1989)
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