1-甲氧基-2-萘甲酸
1-甲氧基-2-萘甲酸结构式
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常用名 | 1-甲氧基-2-萘甲酸 | 英文名 | 1-METHOXY-2-NAPHTHOIC ACID |
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| CAS号 | 883-21-6 | 分子量 | 202.20600 | |
| 密度 | 1.263g/cm3 | 沸点 | 358.8ºC at 760 mmHg | |
| 分子式 | C12H10O3 | 熔点 | 125-129ºC(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 142.1ºC |
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The trifluoromethoxy group: a long-range electron-withdrawing substituent.
Chemistry 8(4) , 799-804, (2002) Judged by its capacity to promote a hydrogen/metal permutation at an ortho position, the trifluoromethoxy group is superior to both the methoxy and trifluoromethyl groups. Moreover, like CF(3) and unlike OCH(3), OCF(3) exerts a long-range effect that still co... |
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ortho-Lithium/magnesium carboxylate-driven aromatic nucleophilic substitution reactions on unprotected naphthoic acids.
J. Org. Chem. 77(1) , 718-24, (2012) Substitution of an ortho-fluoro or methoxy group in 1- and 2-naphthoic acids furnishing substituted naphthoic acids occurs in good to excellent yields upon reaction with alkyl/vinyl/aryl organolithium and Grignard reagents, in the absence of a metal catalyst ... |
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The metalation of 1-methoxynaphthalene with n-butyllithium. Graybill BM and Shirley DA.
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Chemistry of aryloxazolines. Applications to the synthesis of lignan lactone derivatives. Meyers AI and Avila WB.
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