1-METHOXY-2-NAPHTHOIC ACID
1-METHOXY-2-NAPHTHOIC ACID structure
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Common Name | 1-METHOXY-2-NAPHTHOIC ACID | ||
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| CAS Number | 883-21-6 | Molecular Weight | 202.20600 | |
| Density | 1.263g/cm3 | Boiling Point | 358.8ºC at 760 mmHg | |
| Molecular Formula | C12H10O3 | Melting Point | 125-129ºC(lit.) | |
| MSDS | Chinese USA | Flash Point | 142.1ºC | |
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The trifluoromethoxy group: a long-range electron-withdrawing substituent.
Chemistry 8(4) , 799-804, (2002) Judged by its capacity to promote a hydrogen/metal permutation at an ortho position, the trifluoromethoxy group is superior to both the methoxy and trifluoromethyl groups. Moreover, like CF(3) and unlike OCH(3), OCF(3) exerts a long-range effect that still co... |
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ortho-Lithium/magnesium carboxylate-driven aromatic nucleophilic substitution reactions on unprotected naphthoic acids.
J. Org. Chem. 77(1) , 718-24, (2012) Substitution of an ortho-fluoro or methoxy group in 1- and 2-naphthoic acids furnishing substituted naphthoic acids occurs in good to excellent yields upon reaction with alkyl/vinyl/aryl organolithium and Grignard reagents, in the absence of a metal catalyst ... |
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Birch Reduction of 2-Naphthoic and of ortho-Methoxynaphthoic Acids. Eliel EL and Hoover TE.
J. Org. Chem. 24(7) , 938-942, (1959)
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The metalation of 1-methoxynaphthalene with n-butyllithium. Graybill BM and Shirley DA.
J. Org. Chem. 31(4) , 1221-1225, (1966)
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Chemistry of aryloxazolines. Applications to the synthesis of lignan lactone derivatives. Meyers AI and Avila WB.
J. Org. Chem. 46(19) , 3881-3886, (1981)
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