2-Naphthyl trifluoromethanesulfonate
Modify Date: 2024-01-10 19:02:12
2-Naphthyl trifluoromethanesulfonate structure
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Common Name | 2-Naphthyl trifluoromethanesulfonate | ||
|---|---|---|---|---|
| CAS Number | 3857-83-8 | Molecular Weight | 276.23200 | |
| Density | 1.493g/cm3 | Boiling Point | 343.8ºC at 760 mmHg | |
| Molecular Formula | C11H7F3O3S | Melting Point | 30-32ºC(lit.) | |
| MSDS | Chinese USA | Flash Point | >230 °F | |
| Symbol |
GHS05 |
Signal Word | Danger | |
| Name | naphthalen-2-yl trifluoromethanesulfonate |
|---|---|
| Synonym | More Synonyms |
| Density | 1.493g/cm3 |
|---|---|
| Boiling Point | 343.8ºC at 760 mmHg |
| Melting Point | 30-32ºC(lit.) |
| Molecular Formula | C11H7F3O3S |
| Molecular Weight | 276.23200 |
| Flash Point | >230 °F |
| Exact Mass | 276.00700 |
| PSA | 51.75000 |
| LogP | 4.14900 |
| Index of Refraction | 1.56 |
| Symbol |
GHS05 |
|---|---|
| Signal Word | Danger |
| Hazard Statements | H314 |
| Precautionary Statements | P280-P305 + P351 + P338-P310 |
| Personal Protective Equipment | Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges |
| Hazard Codes | C: Corrosive; |
| Risk Phrases | 34 |
| Safety Phrases | 22-26-27-36/37/39-45 |
| RIDADR | UN 3261 8/PG 2 |
| HS Code | 2906299090 |
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~96%
2-Naphthyl trif... CAS#:3857-83-8 |
| Literature: Brimble, Margaret A.; Lai, Michelle Y.H. Organic and Biomolecular Chemistry, 2003 , vol. 1, # 12 p. 2084 - 2095 |
|
~99%
2-Naphthyl trif... CAS#:3857-83-8 |
| Literature: Boisnard, Sabine; Chastanet, Jaqueline; Zhu, Jieping Tetrahedron Letters, 1999 , vol. 40, # 42 p. 7469 - 7472 |
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~94%
2-Naphthyl trif... CAS#:3857-83-8 |
| Literature: Jean, Mickael; Renaulty, Jacques; Uriac, Philippe; Capet, Marc; Van De Weghe, Pierre Organic Letters, 2007 , vol. 9, # 18 p. 3623 - 3625 |
|
~%
2-Naphthyl trif... CAS#:3857-83-8 |
| Literature: DAIICHI PHARMACEUTICAL CO., LTD. Patent: EP949238 A1, 1999 ; |
|
~72%
2-Naphthyl trif... CAS#:3857-83-8 |
| Literature: Effenberger; Mack Tetrahedron Letters, 1970 , p. 3947 |
|
~%
2-Naphthyl trif... CAS#:3857-83-8 |
| Literature: Gmelin Handbook: F: PerFHalOrg.2, 1.3.4, page 137 - 166 |
|
~%
2-Naphthyl trif... CAS#:3857-83-8 |
| Literature: Hendrickson,J.B.; Bergeron,R. Tetrahedron Letters, 1973 , # 46 p. 4607 - 4610 |
![1H-Imidazole,1-[(trifluoromethyl)sulfonyl]- structure](https://www.chemsrc.com/caspic/277/29540-81-6.png)
| Precursor 10 | |
|---|---|
| DownStream 10 | |
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CAS#:612-94-2| HS Code | 2906299090 |
|---|---|
| Summary | 2906299090 other aromatic alcohols。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0% |
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Palladium-catalyzed conversion of aryl and vinyl triflates to bromides and chlorides.
J. Am. Chem. Soc. 132 , 14076, (2010) The palladium-catalyzed conversion of aryl and vinyl triflates to aryl and vinyl halides (bromides and chlorides) has been developed using dialkylbiaryl phosphine ligands. A variety of aryl, heteroary... |
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Regiochemical control and suppression of double bond isomerization in the Heck arylation of 1-(methoxycarbonyl)-2, 5-dihydropyrrole. Sonesson C, et al.
J. Org. Chem. 61(14) , 4756-4763, (1996)
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Influence of the catalyst on the Pd0-mediated reactions of BrZnCH(CH3) COOtBu with vinyl and aryl triflates. Orsini F, et al.
J. Organomet. Chem. 367(3) , 375-382, (1989)
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| 2-naphthol triflate |
| MFCD00192341 |
| 2-naphthyl triflate |
| 2-Naphthyl Trifluoromethanesulfonate |
| Trifluoromethanesulfonic Acid 2-Naphthyl Ester |
| naphthyl-OTf |
| trifluoromethanesulfonic acid naphthalen-2-yl ester |