2,2,2-Trifluoroethyl formate structure
|
Common Name | 2,2,2-Trifluoroethyl formate | ||
|---|---|---|---|---|
| CAS Number | 32042-38-9 | Molecular Weight | 128.050 | |
| Density | 1.3±0.1 g/cm3 | Boiling Point | 33.7±40.0 °C at 760 mmHg | |
| Molecular Formula | C3H3F3O2 | Melting Point | N/A | |
| MSDS | Chinese USA | Flash Point | -17.7±19.6 °C | |
| Symbol |
GHS02, GHS07 |
Signal Word | Danger | |
| Name | 2,2,2-trifluoroethyl formate |
|---|---|
| Synonym | More Synonyms |
| Density | 1.3±0.1 g/cm3 |
|---|---|
| Boiling Point | 33.7±40.0 °C at 760 mmHg |
| Molecular Formula | C3H3F3O2 |
| Molecular Weight | 128.050 |
| Flash Point | -17.7±19.6 °C |
| Exact Mass | 128.008514 |
| PSA | 26.30000 |
| LogP | 1.07 |
| Vapour Pressure | 547.2±0.1 mmHg at 25°C |
| Index of Refraction | 1.300 |
| InChIKey | CAFROQYMUICGNO-UHFFFAOYSA-N |
| SMILES | O=COCC(F)(F)F |
| Storage condition | Flammables area |
| Symbol |
GHS02, GHS07 |
|---|---|
| Signal Word | Danger |
| Hazard Statements | H225-H302-H319 |
| Precautionary Statements | P210-P305 + P351 + P338 |
| Personal Protective Equipment | Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
| Hazard Codes | F,Xn |
| Risk Phrases | R11 |
| Safety Phrases | 26 |
| RIDADR | UN 1993 3/PG 2 |
| Packaging Group | II |
| Hazard Class | 3.0 |
| HS Code | 2915120000 |
|
~70%
2,2,2-Trifluoro... CAS#:32042-38-9 |
| Literature: Hill, David R; Hsiao, Chi-Nung; Kurukulasuriya, Ravi; Wittenberger, Steven J Organic letters, 2002 , vol. 4, # 1 p. 111 - 113 |
|
~%
2,2,2-Trifluoro... CAS#:32042-38-9 |
| Literature: US2002/19539 A1, ; US 20020019539 A1 |
|
~84%
2,2,2-Trifluoro... CAS#:32042-38-9 |
| Literature: Environmental Science and Technology, , vol. 38, # 21 p. 5567 - 5576 |
|
~%
2,2,2-Trifluoro... CAS#:32042-38-9 |
| Literature: Environmental Science and Technology, , vol. 36, # 14 p. 3118 - 3123 |
|
~%
2,2,2-Trifluoro... CAS#:32042-38-9 |
| Literature: Chemical Physics Letters, , vol. 524, p. 32 - 37 |
|
~%
2,2,2-Trifluoro... CAS#:32042-38-9 |
| Literature: ChemPhysChem, , vol. 14, # 16 p. 3834 - 3842 |
|
~%
2,2,2-Trifluoro... CAS#:32042-38-9 |
| Literature: ChemPhysChem, , vol. 14, # 16 p. 3834 - 3842 |
| Precursor 6 | |
|---|---|
| DownStream 5 | |
| HS Code | 2915120000 |
|---|---|
| Summary | 2915120000 salts of formic acid。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0% |
|
2,2,2-trifluoroethyl formate: a versatile and selective reagent for the formylation of alcohols, amines, and N-hydroxylamines.
Org. Lett. 4 , 111, (2002) [reaction: see text] Treatment of a variety of alcohols, amines, and N-hydroxylamines with 2,2,2-trifluoroethyl formate gave the corresponding formylated adducts in high yields. |
| Zayia's reagent |
| HCOOCH2CF3 |
| TFEF |
| Formic Acid 2,2,2-Trifluoroethyl Ester |
| Ameisensaeure-2,2,2-trifluorethylester |
| Ethanol, 2,2,2-trifluoro-, formate |
| 2,2,2-Trifluoroethyl formate |
| trifluoroethyl formate |
| 2,2,2-trifluoroethylformate |