2,2,2-Trifluoroethyl formate

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
33.7±40.0 °C at 760 mmHg

[ Molecular Formula ]:
C₃H₃F₃O₂

[ Molecular Weight ]:
128.050

[ Flash Point ]:
-17.7±19.6 °C

[ Exact Mass ]:
128.008514

[ PSA ]:
26.30000

[ LogP ]:
1.07

[ Vapour Pressure ]:
547.2±0.1 mmHg at 25°C

[ Index of Refraction ]:
1.300

[ Storage condition ]:
Flammables area

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[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H302-H319

[ Precautionary Statements ]:
P210-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F,Xn

[ Risk Phrases ]:
R11

[ Safety Phrases ]:
26

[ RIDADR ]:
UN 1993 3/PG 2

[ Packaging Group ]:
II

[ Hazard Class ]:
3.0

[ HS Code ]:
2915120000

Click to get detail synthetic route

Precursor

DownStream

[ HS Code ]: 2915120000

[ Summary ]:
2915120000 salts of formic acid。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

2,2,2-trifluoroethyl formate: a versatile and selective reagent for the formylation of alcohols, amines, and N-hydroxylamines.

Org. Lett. 4 , 111, (2002)

[reaction: see text] Treatment of a variety of alcohols, amines, and N-hydroxylamines with 2,2,2-trifluoroethyl formate gave the corresponding formylated adducts in high yields.

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