Tetrahedron

Trimethysilyl triflate in organic synthesis11Part 11 of this series. Part 10: S. Murata and R. Noyori, Tetrahedron Letters 2107 (1981).

R Noyori, S Murata, M Suzuki

Index: Noyori, R.; Murata, S.; Suzuki, M. Tetrahedron, 1981 , vol. 37, # 23 p. 3899 - 3910

Full Text: HTML

Citation Number: 321

Abstract

Trimethylsilyl triflate is a powerful silylating agent for organic compounds and acts as a catalyst which accelerates a variety of nucleophilic reactions in aprotic media. The reactions proceed via one-center, electrophilic coordination of the silyl group to hetero functional groups and exhibit unique selectivities.

 Related Synthetic Route

~6%

Learn More

~72%

Learn More

~99%

Learn More

~99%

Learn More

~94%

Learn More

~98%

Learn More

~99%

Learn More

~75%

Learn More

~85%

Learn More

~88%

Learn More

~99%

Learn More

~%

Learn More

~%

Learn More

~38%

Learn More

~91%

Learn More

~81%

Learn More

~99%

Learn More

~97%

Learn More

~95%

Learn More