Trimethylsilyl cyanide structure
|
Common Name | Trimethylsilyl cyanide | ||
|---|---|---|---|---|
| CAS Number | 7677-24-9 | Molecular Weight | 99.206 | |
| Density | 0.8±0.1 g/cm3 | Boiling Point | 118.5±0.0 °C at 760 mmHg | |
| Molecular Formula | C4H9NSi | Melting Point | 8-11 °C(lit.) | |
| MSDS | Chinese USA | Flash Point | 1.1±0.0 °C | |
| Symbol |
GHS02, GHS06 |
Signal Word | Danger | |
| Name | Trimethylsilyl Cyanide |
|---|---|
| Synonym | More Synonyms |
| Density | 0.8±0.1 g/cm3 |
|---|---|
| Boiling Point | 118.5±0.0 °C at 760 mmHg |
| Melting Point | 8-11 °C(lit.) |
| Molecular Formula | C4H9NSi |
| Molecular Weight | 99.206 |
| Flash Point | 1.1±0.0 °C |
| Exact Mass | 99.050423 |
| PSA | 23.79000 |
| LogP | 1.00 |
| Vapour Pressure | 16.6±0.2 mmHg at 25°C |
| Index of Refraction | 1.388 |
| Storage condition | 0-6°C |
| Water Solubility | reacts |
| Symbol |
GHS02, GHS06 |
|---|---|
| Signal Word | Danger |
| Hazard Statements | H225-H300 + H310 + H330 |
| Supplemental HS | Contact with water liberates toxic gas. |
| Precautionary Statements | P210-P260-P264-P280-P284-P301 + P310 |
| Personal Protective Equipment | Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
| Hazard Codes | F:Flammable |
| Risk Phrases | R11;R26/27/28;R29;R50/53 |
| Safety Phrases | S16-S36/37/39-S45-S61-S28A-S26 |
| RIDADR | UN 3384 6.1/PG 1 |
| WGK Germany | 3 |
| Packaging Group | II |
| Hazard Class | 6.1 |
| HS Code | 29310095 |
| Precursor 10 | |
|---|---|
| DownStream 9 | |
| HS Code | 2931900090 |
|---|---|
| Summary | 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0% |
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Asymmetric activation of tropos 2,2'-biphenol with cinchonine generates an effective catalyst for the asymmetric strecker reaction of N-tosyl-protected aldimines and ketoimines.
Angew. Chem. Int. Ed. Engl. 46(44) , 8468-70, (2007)
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A chemoselective Ugi-type reaction in water using TMSCN as a functional isonitrile equivalent: generation of heteroaromatic molecular diversity.
Org. Biomol. Chem. 10(46) , 9271-7, (2012) KF-mediated nucleophilic activation of TMSCN as a functional isonitrile equivalent establishes an efficient and chemoselective Ugi-type multicomponent reaction of a heterocyclic amidine and aldehyde w... |
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Sc₂(pydc)₂ unit based 1D, 2D and 3D metal-organic frameworks as heterogeneous Lewis acid catalysts for cyanosilylation.
Dalton Trans. 44(4) , 1942-7, (2014) Three scandium metal-organic frameworks (Sc-MOFs), [Sc(pydc)(Hpydc)(H2O)]·H2O (1), [Sc2(pydc)3(H2O)4]·5H2O (2) and [Sc(pydc)(H2O)(NO3)] (3) with similar Sc2(pydc)2 building unit were prepared by using... |
| Trimethylsilyl cyanide |
| trimethylsilylformonitrile |
| EINECS 231-657-3 |
| Silanecarbonitrile, 1,1,1-trimethyl- |
| Trimethylsilanecarbonitrile |
| MFCD00001765 |
| Silanecarbonitrile, trimethyl- |
| TRIMETHYLSILYLCYANIDE |