Trimethylsilyl cyanide

Modify Date: 2024-01-02 18:16:49

Trimethylsilyl cyanide Structure
Trimethylsilyl cyanide structure
Common Name Trimethylsilyl cyanide
CAS Number 7677-24-9 Molecular Weight 99.206
Density 0.8±0.1 g/cm3 Boiling Point 118.5±0.0 °C at 760 mmHg
Molecular Formula C4H9NSi Melting Point 8-11 °C(lit.)
MSDS Chinese USA Flash Point 1.1±0.0 °C
Symbol GHS02 GHS06
GHS02, GHS06
Signal Word Danger

 Names

Name Trimethylsilyl Cyanide
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.8±0.1 g/cm3
Boiling Point 118.5±0.0 °C at 760 mmHg
Melting Point 8-11 °C(lit.)
Molecular Formula C4H9NSi
Molecular Weight 99.206
Flash Point 1.1±0.0 °C
Exact Mass 99.050423
PSA 23.79000
LogP 1.00
Vapour Pressure 16.6±0.2 mmHg at 25°C
Index of Refraction 1.388
Storage condition 0-6°C
Water Solubility reacts

 Safety Information

Symbol GHS02 GHS06
GHS02, GHS06
Signal Word Danger
Hazard Statements H225-H300 + H310 + H330
Supplemental HS Contact with water liberates toxic gas.
Precautionary Statements P210-P260-P264-P280-P284-P301 + P310
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes F:Flammable
Risk Phrases R11;R26/27/28;R29;R50/53
Safety Phrases S16-S36/37/39-S45-S61-S28A-S26
RIDADR UN 3384 6.1/PG 1
WGK Germany 3
Packaging Group II
Hazard Class 6.1
HS Code 29310095

 Customs

HS Code 2931900090
Summary 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

 Articles28

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A chemoselective Ugi-type reaction in water using TMSCN as a functional isonitrile equivalent: generation of heteroaromatic molecular diversity.

Org. Biomol. Chem. 10(46) , 9271-7, (2012)

KF-mediated nucleophilic activation of TMSCN as a functional isonitrile equivalent establishes an efficient and chemoselective Ugi-type multicomponent reaction of a heterocyclic amidine and aldehyde w...

Sc₂(pydc)₂ unit based 1D, 2D and 3D metal-organic frameworks as heterogeneous Lewis acid catalysts for cyanosilylation.

Dalton Trans. 44(4) , 1942-7, (2014)

Three scandium metal-organic frameworks (Sc-MOFs), [Sc(pydc)(Hpydc)(H2O)]·H2O (1), [Sc2(pydc)3(H2O)4]·5H2O (2) and [Sc(pydc)(H2O)(NO3)] (3) with similar Sc2(pydc)2 building unit were prepared by using...

 Synonyms

Trimethylsilyl cyanide
trimethylsilylformonitrile
EINECS 231-657-3
Silanecarbonitrile, 1,1,1-trimethyl-
Trimethylsilanecarbonitrile
MFCD00001765
Silanecarbonitrile, trimethyl-
TRIMETHYLSILYLCYANIDE
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