Bulletin of the Chemical Society of Japan

Solid Acid and Base-Catalyzed Cyanosilylation of Carbonyl Compounds with Cyanotrimethylsilane.

K Higuchi, M Onaka, Y Izumi

Index: Higuchi, Katsumi; Onaka, Makoto; Izumi, Yusuke Bulletin of the Chemical Society of Japan, 1993 , vol. 66, # 7 p. 2016 - 2032

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Citation Number: 100

Abstract

A new attempt was investigated to utilize inorganic solid acids and bases for the promotion of the reaction of cyanotrimethylsilane (Me 3 SiCN) with carbonyl compounds. Strongly acidic solids, such as Sn 4+ ion-exchanged montmorillonite (Sn-Mont) and Fe 3+ ion- exchanged montmorillonite (Fe-Mont), as well as basic solids, such as calcium fluoride (CaF 2), hydroxyapatite (HAp), calcium oxide (CaO), and magnesium oxide (MgO), catalyzed ...