Synthetic Communications

S-Cyanosilylenolethers: Preparation and Potential Intermediates in Synthesis

M Samson, M Vandewalle

Index: Samson,M.; Vandewalle,M. Synthetic Communications, 1978 , vol. 8, p. 231 - 239

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Citation Number: 2

Abstract

Abstract In a previous paper we reported the direct α-phenylsulfenylation of enolates generated during different 1, 4-addition reactions on α, β-unsaturated ketones1. Since Nagata has shown that the conjugate addition of a cyano group with diethylaluminum cyanide leads to an aluminum enolate2, 3, it would be worthwile to investigate the potentiality of this reagent for simultaneous functionalisation at the α-position. Initial ...