Tetrahedron

Trimethysilyl triflate in organic synthesis11Part 11 of this series. Part 10: S. Murata and R. Noyori, Tetrahedron Letters 2107 (1981).

R Noyori, S Murata, M Suzuki

文献索引：Noyori, R.; Murata, S.; Suzuki, M. Tetrahedron, 1981 , vol. 37, # 23 p. 3899 - 3910

被引用次数: 321

摘要

Trimethylsilyl triflate is a powerful silylating agent for organic compounds and acts as a catalyst which accelerates a variety of nucleophilic reactions in aprotic media. The reactions proceed via one-center, electrophilic coordination of the silyl group to hetero functional groups and exhibit unique selectivities.

~6%

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~72%

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~99%

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~99%

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~94%

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~98%

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~99%

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~75%

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~85%

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~88%

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~99%

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~38%

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~91%

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~81%

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~99%

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~97%

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~95%

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