e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521

Organic letters

Palladium (II)-Catalyzed Sequential Hydroxylation-Carboxylation of Biphenyl Using Formic Acid as a Carbonyl Source

F Shibahara, S Kinoshita, K Nozaki

Index: Organic Letters, , vol. 6, # 14 p. 2437 - 2439

Full Text: HTML

Citation Number: 30

Abstract

... Volume: Page: Digital Object Identifier (DOI). ... Organic Letters. ... The cleavage and functionalization of an unreactive C−H bond by the aid of transition metal catalysts is one of the hottest topics in organic and organometallic chemistry. ...

Formic Acid Structure

Cumene Structure

~%

4-Isopropylbenzoic acid Structure

4-Isopropylbenz...

3-Isopropylbenzoic acid Structure

3-Isopropylbenz...

Detail

Biphenyl Structure

carbon monoxide Structure

carbon monoxide

~%

9-Fluorenone Structure

3-Biphenylcarboxylic acid Structure

3-Biphenylcarbo...

Detail

Formic Acid Structure

Biphenyl Structure

~18%

6H-Dibenzo[b,d]pyran-6-one Structure

6H-Dibenzo[b,d]...

3-Biphenylcarboxylic acid Structure

3-Biphenylcarbo...

Detail

Formic Acid Structure

benzene Structure

~%

benzoic acid Structure

Salicylic acid Structure

Detail

Formic Acid Structure

phenyl acetate Structure

~%

Salicylic acid Structure

4-Hydroxybenzoic acid Structure

4-Hydroxybenzoi...

Formic Acid Structure

4-(Trifluoroacetyl)-diphenyl ether Structure

4-(Trifluoroace...

~%

4'-Hydroxy-4-biphenylcarboxylic acid Structure

4'-Hydroxy-4-bi...

4'-HYDROXYBIPHENYL-3-CARBOXYLICACID Structure

4'-HYDROXYBIPHE...

Formic Acid Structure

1,1'-biphenyl-4-yl formate Structure

1,1'-biphenyl-4...

~%

4'-Hydroxy-4-biphenylcarboxylic acid Structure

4'-Hydroxy-4-bi...

4'-HYDROXYBIPHENYL-3-CARBOXYLICACID Structure

4'-HYDROXYBIPHE...

Formic Acid Structure

Biphenyl Structure

~%

4,4'-Dihydroxybiphenyl Structure

4,4'-Dihydroxyb...

4'-Hydroxy-4-biphenylcarboxylic acid Structure

4'-Hydroxy-4-bi...

Detail

Formic Acid Structure

Toluene Structure

~%

2-Methylbenzoic acid Structure

2-Methylbenzoic acid

4-Methylbenzoic acid Structure

4-Methylbenzoic acid

Detail

Formic Acid Structure

Biphenyl Structure

~8%

6H-Dibenzo[b,d]pyran-6-one Structure

6H-Dibenzo[b,d]...

3-Biphenylcarboxylic acid Structure

3-Biphenylcarbo...

Detail

Formic Acid Structure

Cumene Structure

~%

4-Isopropylbenzoic acid Structure

4-Isopropylbenz...

3-Isopropylbenzoic acid Structure

3-Isopropylbenz...

Detail

Formic Acid Structure

Chlorobenzene Structure

~%

4-Chlorobenzoic acid Structure

4-Chlorobenzoic acid

3-Chlorobenzoic Acid Structure

3-Chlorobenzoic Acid

Detail

Formic Acid Structure

Iodobenzene Structure

~%

4-Iodobenzoic acid Structure

4-Iodobenzoic acid

2-Iodobenzoic acid Structure

2-Iodobenzoic acid

Detail

Formic Acid Structure

Iodobenzene Structure

~%

4-Iodobenzoic acid Structure

4-Iodobenzoic acid

2-Iodobenzoic acid Structure

2-Iodobenzoic acid

Detail

Formic Acid Structure

4-(Trifluoroacetyl)-diphenyl ether Structure

4-(Trifluoroace...

~%

4'-Hydroxy-4-biphenylcarboxylic acid Structure

4'-Hydroxy-4-bi...

4'-HYDROXYBIPHENYL-3-CARBOXYLICACID Structure

4'-HYDROXYBIPHE...

Formic Acid Structure

1,1'-biphenyl-4-yl formate Structure

1,1'-biphenyl-4...

~%

4'-Hydroxy-4-biphenylcarboxylic acid Structure

4'-Hydroxy-4-bi...

4'-HYDROXYBIPHENYL-3-CARBOXYLICACID Structure

4'-HYDROXYBIPHE...

Formic Acid Structure

Biphenyl Structure

~%

4,4'-Dihydroxybiphenyl Structure

4,4'-Dihydroxyb...

4'-Hydroxy-4-biphenylcarboxylic acid Structure

4'-Hydroxy-4-bi...

Detail

Formic Acid Structure

Biphenyl Structure

~%

4,4'-Dihydroxybiphenyl Structure

4,4'-Dihydroxyb...

4'-Hydroxy-4-biphenylcarboxylic acid Structure

4'-Hydroxy-4-bi...

Detail

Biphenyl Structure

carbon monoxide Structure

carbon monoxide

~%

9-Fluorenone Structure

3-Biphenylcarboxylic acid Structure

3-Biphenylcarbo...

Detail

Formic Acid Structure

Biphenyl Structure

~5%

6H-Dibenzo[b,d]pyran-6-one Structure

6H-Dibenzo[b,d]...

3-Biphenylcarboxylic acid Structure

3-Biphenylcarbo...

Detail

Formic Acid Structure

Toluene Structure

~%

2-Methylbenzoic acid Structure

2-Methylbenzoic acid

4-Methylbenzoic acid Structure

4-Methylbenzoic acid

Detail

Formic Acid Structure

Iodobenzene Structure

~%

4-Iodobenzoic acid Structure

4-Iodobenzoic acid

2-Iodobenzoic acid Structure

2-Iodobenzoic acid

Detail

Formic Acid Structure

benzene Structure

~%

benzoic acid Structure

Salicylic acid Structure

Detail

Formic Acid Structure

phenyl acetate Structure

~%

Salicylic acid Structure

4-Hydroxybenzoic acid Structure

4-Hydroxybenzoi...

Formic Acid Structure

Toluene Structure

~%

2-Methylbenzoic acid Structure

2-Methylbenzoic acid

4-Methylbenzoic acid Structure

4-Methylbenzoic acid

Detail

Formic Acid Structure

Chlorobenzene Structure

~%

4-Chlorobenzoic acid Structure

4-Chlorobenzoic acid

3-Chlorobenzoic Acid Structure

3-Chlorobenzoic Acid

Detail

13C magnetic resonance studies. 142. The fate of highly subs...

[Dyllick-Brenzinger, Rainer A.; Patel, Vijay; Rampersad, Mollin B.; Stothers, J. B.; Thomas, Shirley E. Canadian Journal of Chemistry, 1990 , vol. 68, # 7 p. 1106 - 1115]

Photochemistry of cyclopropene derivatives. 20. Deuterium is...

[Journal of the American Chemical Society, , vol. 103, # 11 p. 3057 - 3068]

Pincer thioamide and pincer thioimide palladium complexes ca...

[Chemistry - A European Journal, , vol. 15, # 6 p. 1499 - 1507]

Pincer thioamide and pincer thioimide palladium complexes ca...

[Chemistry - A European Journal, , vol. 15, # 6 p. 1499 - 1507]

13C magnetic resonance studies. 142. The fate of highly subs...

[Canadian Journal of Chemistry, , vol. 68, # 7 p. 1106 - 1115]