(-)-Diethyl D-tartrate

(-)-Diethyl D-tartrate Structure
(-)-Diethyl D-tartrate structure
Common Name (-)-Diethyl D-tartrate
CAS Number 13811-71-7 Molecular Weight 206.193
Density 1.3±0.1 g/cm3 Boiling Point 280.0±0.0 °C at 760 mmHg
Molecular Formula C8H14O6 Melting Point 17ºC
MSDS USA Flash Point 93.3±0.0 °C

Bioplastics from feather quill.

Biomacromolecules 12(10) , 3826-32, (2011)

Poultry feather quills have been extruded in a twin screw extruder with sodium sulfite treatment as a reducing agent. The effect of four different plasticizers (ethylene glycol, propylene glycol, glycerol, and diethyl tartrate) on the thermoplastic properties...

Separation of corticosteroids by microemulsion EKC with diethyl L-tartrate as the oil phase.

Electrophoresis 28(20) , 3691-6, (2007)

A novel microemulsion based on a mixture of diethyl L-tartrate (DET) and SDS was developed for the microemulsion EKC (MEEKC) determination of structurally related steroids. The system consisted of 0.5% w/w DET, 1.7% w/w SDS, 1.2% w/w 1-butanol, 89.6% w/w phos...

A practical and azide-free synthetic approach to oseltamivir from diethyl D-tartrate.

J. Org. Chem. 75(9) , 3125-8, (2010)

A short and practical synthesis of oseltamivir was accomplished in 11 steps from inexpensive and abundant diethyl D-tartrate starting material. This azide-free route featured an asymmetric aza-Henry reaction and a domino nitro-Michael/Horner-Wadsworth-Emmons ...

Two-chiral component microemulsion EKC - chiral surfactant and chiral oil. Part 2: diethyl tartrate.

Electrophoresis 28(15) , 2644-57, (2007)

In this second study on dual-chirality microemulsions containing a chiral surfactant and a chiral oil, a less hydrophobic and lower interfacial tension chiral oil, diethyl tartrate, is employed (Part 1, Foley, J. P. et al.., Electrophoresis, DOI: 10.1002/elps...

Total synthesis of broussonetine F: the orthoamide Overman rearrangement of an allylic diol.

Org. Lett. 13(4) , 616-9, (2011)

A first total synthesis of broussonetine F from diethyl L-tartrate was achieved. The cornerstone of our synthesis was an orthoamide Overman rearrangement, which provided an allylic amino alcohol with complete diastereoselectivity.

Influence of microemulsion chirality on chromatographic figures of merit in EKC: results with novel three-chiral-component microemulsions and comparison with one- and two-chiral-component microemulsions.

Electrophoresis 28(17) , 3024-40, (2007)

Novel microemulsion formulations containing all chiral components are described for the enantioseparation of six pairs of pharmaceutical enantiomers (atenolol, ephedrine, metoprolol, N-methyl ephedrine, pseudoephedrine, and synephrine). The chiral surfactant ...

Total syntheses of naturally occurring diacetylenic spiroacetal enol ethers.

J. Org. Chem. 70(15) , 6045-52, (2005)

A highly stereoselective method for constructing a (2E)-methoxymethylidene-1,6-dioxaspiro[4.5]decane skeleton has been developed on the basis of the palladium(II)-catalyzed ring-closing reaction of the 3,4-dioxygenated-9-hydroxy-1-nonyn-5-one derivatives as a...

Total synthesis of the light-harvesting carotenoid peridinin.

Angew. Chem. Int. Ed. Engl. 45(24) , 4023-7, (2006)

Pseudo-first-order alkaline hydrolysis of diethyl tartrate: a baseline study for a polymer matrix used in controlled-release delivery systems.

J. Pharm. Sci. 79(4) , 364-8, (1990)

The hydrolysis kinetics of a bifunctional group compound, diethyl tartrate, was studied as a function of temperature and pH in the alkaline region. A pH-stat was used to maintain constant pH conditions in the alkaline region. This allowed the studies to be ca...