2-bromo-3-methylbut-2-ene
2-bromo-3-methylbut-2-ene structure
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Common Name | 2-bromo-3-methylbut-2-ene | ||
|---|---|---|---|---|
| CAS Number | 3017-70-7 | Molecular Weight | 149.02900 | |
| Density | 1.284 g/mL at 25ºC(lit.) | Boiling Point | 40ºC75 mm Hg(lit.) | |
| Molecular Formula | C5H9Br | Melting Point | -106.7°C (estimate) | |
| MSDS | Chinese USA | Flash Point | 77 °F | |
| Symbol |
GHS02, GHS06 |
Signal Word | Danger | |
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The first total synthesis of the cyclodepsipeptide pipecolidepsin A.
Nat. Commun. 4 , 2352, (2013) Pipecolidepsin A is a head-to-side-chain cyclodepsipeptide isolated from the marine sponge Homophymia lamellosa. This compound shows relevant cytotoxic activity in three human tumour cell lines and has unique structural features, with an abundance of non-prot... |
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Copper-catalyzed halogen exchange in aryl halides: an aromatic Finkelstein reaction.
J. Am. Chem. Soc. 124(50) , 14844-5, (2002) A mild and general method for the conversion of aryl, heteroaryl, and vinyl bromides into the corresponding iodides was developed utilizing a catalyst system comprising 5 mol % of CuI and 10 mol % of a 1,2- or 1,3-diamine ligand. A variety of polar functional... |
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Palladium/di-1-adamantyl-n-butylphosphine-catalyzed reductive carbonylation of aryl and vinyl halides. Brennführer A, et al.
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Synthesis of All the Diastereomers of 2-Amino-3-hydroxy-4, 5-dimethylhexanoic Acid. Spengler J and Albericio F.
European J. Org. Chem. 1 , 44-47, (2014)
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