4-Bromo-1-methoxy-2-methylbenzene
4-Bromo-1-methoxy-2-methylbenzene structure
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Common Name | 4-Bromo-1-methoxy-2-methylbenzene | ||
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| CAS Number | 14804-31-0 | Molecular Weight | 201.061 | |
| Density | 1.4±0.1 g/cm3 | Boiling Point | 226.1±20.0 °C at 760 mmHg | |
| Molecular Formula | C8H9BrO | Melting Point | 66-69 °C(lit.) | |
| MSDS | Chinese USA | Flash Point | 102.3±7.8 °C | |
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A useful Pd-catalyzed Negishi coupling approach to benzylic sulfonamide derivatives.
Org. Lett. 10(12) , 2517-20, (2008) A mild catalytic system to access diversely functionalized benzylic sulfonamides has been developed. Palladium-catalyzed alpha-arylation by Negishi cross-coupling of sulfonamide-stabilized anions and a wide range of aryl iodides, bromides, and triflates const... |
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Synthesis of aromatic bisabolene natural products via palladium-catalyzed cross-couplings of organozinc reagents.
J. Org. Chem. 69(7) , 2461-8, (2004) Aromatic bisabolene derivatives were prepared by two methods involving cross-coupling of organozinc reagents. The first synthesis of (+/-)-glandulone A (10), as well as syntheses of (+/-)-curcuhydroquinone (8) and (+/-)-curcuquinone (9), were accomplished via... |
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