Barban
Barban structure
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Common Name | Barban | ||
|---|---|---|---|---|
| CAS Number | 101-27-9 | Molecular Weight | 258.101 | |
| Density | 1.4±0.1 g/cm3 | Boiling Point | 340.8±32.0 °C at 760 mmHg | |
| Molecular Formula | C11H9Cl2NO2 | Melting Point | 75-76ºC | |
| MSDS | Chinese USA | Flash Point | 159.9±25.1 °C | |
| Symbol |
GHS07, GHS09 |
Signal Word | Warning | |
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Synthesis of polyynes to model the sp-carbon allotrope carbyne.
Nature Chemistry 2(11) , 967-71, (2010) Carbyne is an allotrope of carbon composed of sp-hybridized carbon atoms. Although its formation in the laboratory is suggested, no well-defined sample is described. Interest in carbyne and its potential properties remains intense because of, at least in part... |
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Calcium-decorated carbyne networks as hydrogen storage media.
Nano Lett. 11(7) , 2660-5, (2011) Among the carbon allotropes, carbyne chains appear outstandingly accessible for sorption and very light. Hydrogen adsorption on calcium-decorated carbyne chain was studied using ab initio density functional calculations. The estimation of surface area of carb... |
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The pressure tunning Raman and IR spectral studies on the multinuclear metal carbyne complexes.
Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 61(5) , 995-1000, (2005) The Raman and infrared (IR) spectra of four tungsten metal carbyne complexes I, II, IV and V [Cl(CO)2(L)W[triple bond]CC6H4[triple bond](C[triple bond]CC6H4)n[triple bond]N[triple bond]C[triple bond]]2M (L = TMEDA, n = 0, M = PdI2 or ReCl(CO)3; L = DPPE, n = ... |
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[Infrared and Raman spectra studies on isomultinuclear organometallic carbyne compounds].
Guang Pu Xue Yu Guang Pu Fen Xi 20(5) , 702-3, (2000) The infrared and Raman spectra of five isomultinuclear organometallic carbyne compounds were studied. The results show that the introduction of N atom from TMEDA or P atom from DPPE to W atom (both N and P are strong sigma-donor and weak pi-acceptor) will dec... |
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Silylation of iron-bound carbon monoxide affords a terminal Fe carbyne.
J. Am. Chem. Soc. 133(12) , 4438-46, (2011) A series of monocarbonyl iron complexes in the formal oxidation states 0, +1, and +2 are accessible when supported by a tetradentate tris(phosphino)silyl ligand (SiP(iPr)(3) = [Si(o-C(6)H(4)PiPr(2))(3)](-)). X-ray diffraction (XRD) studies of these carbonyl c... |
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Chromium-carbyne complexes: intermediates for organic synthesis.
Angew. Chem. Int. Ed. Engl. 46(10) , 1719-22, (2007)
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Saccharomyces cerevisiae multidrug transporter Qdr2p (Yil121wp): localization and function as a quinidine resistance determinant.
Antimicrob. Agents Chemother. 48(7) , 2531-7, (2004) This work reports the functional analysis of Saccharomyces cerevisiae open reading frame YIL121w, encoding a member of a family of drug:H(+) antiporters with 12 predicted membrane-spanning segments (DHA12 family). Like its close homologue Qdr1p, Yil121wp was ... |
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Structure-activity relationships in the destruction of cytochrome P-450 mediated by certain ethynyl-substituted compounds in rats.
Biochem. Pharmacol. 29(24) , 3253-5, (1980)
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Graphitic carbon in the Allende meteorite: a microstructural study.
Science 212(4492) , 322-4, (1981) High-resolution transmission electron microscopy, shows that carbon in the Allende carbonaceous chondrite meteorite is predominantly a poorly crystalline graphite. Such material is of interest as an important carrier of the isotopically anomalous noble gases ... |
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[Raman and infrared spectral studies of tungsten organometallic carbyne complex at high external pressure].
Guang Pu Xue Yu Guang Pu Fen Xi 21(5) , 596-8, (2001) The Raman and infrared spectra of complex: [Cl(CO)2 (DPPE) W identical to CC6H4C identical to CC6H4NC]2 Re Cl(CO)3 (DPPE = bis (diphenylphosphino) ethane, (Ph)2PCH2CH2P(Ph)2) were measured at high external pressure (up to about 50 kbar). The pressure induced ... |