1-Chloro-3-fluorobenzene

1-Chloro-3-fluorobenzene Structure
1-Chloro-3-fluorobenzene structure
Common Name 1-Chloro-3-fluorobenzene
CAS Number 625-98-9 Molecular Weight 130.547
Density 1.2±0.1 g/cm3 Boiling Point 127.4±13.0 °C at 760 mmHg
Molecular Formula C6H4ClF Melting Point N/A
MSDS USA Flash Point 20.0±0.0 °C
Symbol GHS02 GHS07
GHS02, GHS07
Signal Word Danger

Formation of benzynes from 2,6-dihaloaryllithiums: mechanistic basis of the regioselectivity.

J. Am. Chem. Soc. 126(45) , 14700-1, (2004)

The key elimination step for the formation of 3-chloro- and 3-fluorobenzyne from 2-chloro-6-fluorophenyllithium displays a pronounced solvent-dependent regioselectivity. 6Li and 13C NMR spectroscopic studies on 2-chloro-6-fluorophenyllithium reveal a single m...

Reactions of dihalobenzene radical cations with ammonia in the gas phase. Reactivity pattern for nucleophilic aromatic substitution. Thölmann D and Gruetzmacher HF.

J. Am. Chem. Soc. 113(9) , 3281-87, (1991)