2-BENZYLOXY-1-METHYLPYRIDINIUM TRIFLUOROMETHANESULFONATE
2-BENZYLOXY-1-METHYLPYRIDINIUM TRIFLUOROMETHANESULFONATE structure
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Common Name | 2-BENZYLOXY-1-METHYLPYRIDINIUM TRIFLUOROMETHANESULFONATE | ||
|---|---|---|---|---|
| CAS Number | 882980-43-0 | Molecular Weight | 349.32500 | |
| Density | N/A | Boiling Point | N/A | |
| Molecular Formula | C14H14F3NO4S | Melting Point | 85-91ºC | |
| MSDS | Chinese USA | Flash Point | N/A | |
| Symbol |
GHS05, GHS07 |
Signal Word | Danger | |
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Mix-and-heat benzylation of alcohols using a bench-stable pyridinium salt.
J. Org. Chem. 71 , 3923, (2006) 2-Benzyloxy-1-methylpyridinium triflate (1) is a stable, neutral organic salt that converts alcohols into benzyl ethers upon warming. The synthesis and reactivity of 1 are described herein. Benzylation of a wide range of alcohols occurs in good to excellent y... |
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Synthesis of benzyl esters using 2-benzyloxy-1-methylpyridinium triflate.
J. Org. Chem. 72 , 8962, (2007) Triethylamine (Et3N) mediates esterification reactions between the title reagent (1) and carboxylic acids. Alcohols, phenols, amides, and other sensitive functionality are not affected; a dual role for Et3N as a promoter and a scavenger is postulated. Benzyl ... |
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Dudley, G. B. et al.
Synlett , 3142, (2005)
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