Ruthenium(II) chloride mesitylene dimer

Ruthenium(II) chloride mesitylene dimer Structure
Ruthenium(II) chloride mesitylene dimer structure
Common Name Ruthenium(II) chloride mesitylene dimer
CAS Number 52462-31-4 Molecular Weight 513.42900
Density N/A Boiling Point N/A
Molecular Formula C18H24Cl2Ru2 Melting Point >300ºC
MSDS Chinese USA Flash Point N/A
Symbol GHS07
GHS07
Signal Word Warning

Highly enantioselective transfer hydrogenation of fluoroalkyl ketones.

Org. Lett. 8 , 5935, (2006)

[Structure: see text] The asymmetric transfer hydrogenation of fluoroalkyl ketones mediated by [Ru(eta6-arene)((S,S)-R2NSO2DPEN)] catalysts using HCO2H-Et3N afforded the corresponding alcohols with high ee's and in excellent yields.

Davies, D. L.; Fawcett, J. et al.

Chem. Commun. (Camb.) , 3151, (1997)