1-Phenylpropane-1,2-dione

1-Phenylpropane-1,2-dione Structure
1-Phenylpropane-1,2-dione structure
Common Name 1-Phenylpropane-1,2-dione
CAS Number 579-07-7 Molecular Weight 148.159
Density 1.1±0.1 g/cm3 Boiling Point 228.0±9.0 °C at 760 mmHg
Molecular Formula C9H8O2 Melting Point <20ºC
MSDS Chinese USA Flash Point 84.4±0.0 °C
Symbol GHS07
GHS07
Signal Word Warning

Identification and characterization of novel benzil (diphenylethane-1,2-dione) analogues as inhibitors of mammalian carboxylesterases.

J. Med. Chem. 48 , 2906-15, (2005)

Carboxylesterases (CE) are ubiquitous enzymes responsible for the metabolism of xenobiotics. Because the structural and amino acid homology among esterases of different classes, the identification of selective inhibitors of these proteins has proved problemat...

Influence of composition on rate of polymerization contraction of light-curing resin composites.

Acta Odontol. Scand. 60(3) , 146-50, (2002)

A slow contraction may result in reduced gap formation when a restorative resin polymerizes in a dental cavity. It was the aim in the present work to investigate the rate of contraction in relation to composition of experimental light-curing resin composites....

Inhibition of the reconstituted mitochondrial oxoglutarate carrier by arginine-specific reagents.

Arch. Biochem. Biophys. 331(1) , 48-54, (1996)

The effect of arginine-specific reagents on the function of the purified and reconstituted oxoglutarate carrier protein of the inner mitochondrial membrane has been investigated. The alpha-dicarbonyl reagents 2,3-butanedione, 2,3-pentanedione, 2,3- and 3,4-he...

Interaction of LED light with coinitiator-containing composite resins: effect of dual peaks.

J. Dent. 40(10) , 836-42, (2012)

Recently the colour stability of composite resins has been an issue due to the emphasis on the aesthetics of restored teeth. The purpose of the present study was to investigate how dual-peak LED units affect the polymerization of coinitiator-containing compos...

In vitro photosensitization initiated by camphorquinone and phenyl propanedione in dental polymeric materials.

J. Photochem. Photobiol. B, Biol. 100(3) , 128-34, (2010)

Documentation is scarce on the photobiological effects of photoinitiators present in dental light curable materials. The aim of this study was to determine cellular effects of the photoinitiators camphorquinone (CQ) and phenyl propanedione (PPD) and to invest...

A combined NMR, DFT, and X-ray investigation of some cinchona alkaloid O-ethers.

J. Org. Chem. 73(17) , 6559-69, (2008)

Structures and conformational behavior of several cinchona alkaloid O-ethers in the solid state (X-ray), in solution (NMR and DFT), and in the gas phase (DFT) were investigated. In the crystal, O-phenylcinchonidine adopts the Open(3) conformation similar to c...

Effect of various visible light photoinitiators on the polymerization and color of light-activated resins.

Dent. Mater. J. 28(4) , 454-60, (2009)

The purpose of this study was to investigate effects of various visible light photoinitiators on the polymerization efficiency and color of the light-activated resins. Four photoinitiators, including camphorquinone, phenylpropanedione, monoacrylphosphine oxid...

Experimental and theoretical analysis of asymmetric induction in heterogeneous catalysis: diastereoselective hydrogenation of chiral alpha-hydroxyketones over Pt catalyst.

J. Am. Chem. Soc. 131(12) , 4449-62, (2009)

Assessing the origin of asymmetric induction in heterogeneously catalyzed hydrogenation is a challenging task. In this work, hydrogenation of a chiral compound, (R)-1-hydroxy-1-phenyl-2-propanone [(R)-PAC], in toluene over cinchonidine modified and unmodified...

Conformational flexibility, UV-induced decarbonylation, and FTIR spectra of 1-phenyl-1,2 propanedione in solid xenon and in the low temperature amorphous phase.

J. Phys. Chem. A 109(25) , 5560-70, (2005)

1-Phenyl-1,2-propanedione has been isolated in low-temperature xenon matrixes and studied by FTIR spectroscopy, supported by DFT(B3LYP)/6-311++G(d,p) calculations. In good agreement with previous electron diffraction data [Shen, Q.; Hagen, K. J. Phys. Chem. 1...

Utilisation of on-line acoustic irradiation as a means to counter-effect catalyst deactivation in heterogeneous catalysis.

Ultrason. Sonochem. 11(3-4) , 233-9, (2004)

The effect of power ultrasound has been studied in the hydrogenation of 1-phenyl-1,2-propanedione (enantioselective hydrogenation) and linoleic acid (fat hardening). Furthermore the hydrogenation of d-xylose to xylitol and citral to citronellal and citronello...