tris(2,2,2-trifluoroethyl)phosphite

tris(2,2,2-trifluoroethyl)phosphite Structure
tris(2,2,2-trifluoroethyl)phosphite structure
Common Name tris(2,2,2-trifluoroethyl)phosphite
CAS Number 370-69-4 Molecular Weight 328.069
Density 1.487 Boiling Point 128.8±40.0 °C at 760 mmHg
Molecular Formula C6H6F9O3P Melting Point N/A
MSDS Chinese USA Flash Point 31.7±27.3 °C
Symbol GHS07
GHS07
Signal Word Warning

A new bis(2,2,2-trifluoroethyl)phosphonate for the synthesis of Z-unsaturated N-methoxy-N-methylamides.

J. Org. Chem. 67(15) , 5437-9, (2002)

The N-methoxy-N-methyl bis(2,2,2-trifluoroethyl)phosphonamide was easily obtained via the Arbuzov reaction with use of commercially available tris(2,2,2-trifluoroethyl)phosphite, 2-bromo-N-methoxy-N-methylacetamide, and KF/alumina. The reaction of bis(2,2,2-t...

Towards a safe lithium-sulfur battery with a flame-inhibiting electrolyte and a sulfur-based composite cathode.

Angew. Chem. Int. Ed. Engl. 53(38) , 10099-104, (2014)

Of the various beyond-lithium-ion batteries, lithium-sulfur (Li-S) batteries were recently reported as possibly being the closest to market. However, its theoretically high energy density makes it potentially hazardous under conditions of abuse. Therefore, ad...