Dichlorobis(dicyclohexyl-1-piperidinylphosphine)palladium(II)
Dichlorobis(dicyclohexyl-1-piperidinylphosphine)palladium(II) structure
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Common Name | Dichlorobis(dicyclohexyl-1-piperidinylphosphine)palladium(II) | ||
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| CAS Number | 1227935-55-8 | Molecular Weight | 740.15900 | |
| Density | N/A | Boiling Point | N/A | |
| Molecular Formula | C34H64Cl2N2P2Pd | Melting Point | N/A | |
| MSDS | Chinese USA | Flash Point | N/A | |
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Cyanation of aryl bromides with K4[Fe(CN)6] catalyzed by dichloro[bis{1-(dicyclohexylphosphanyl)piperidine}]palladium, a molecular source of nanoparticles, and the reactions involved in the catalyst-deactivation processes.
Chemistry 18(10) , 2978-86, (2012) Dichloro[bis{1-(dicyclohexylphosphanyl)piperidine}]palladium [(P{(NC(5)H(10))(C(6)H(11))(2)})(2)PdCl(2)] (1) is a highly active and generally applicable C-C cross-coupling catalyst. Apart from its high catalytic activity in Suzuki, Heck, and Negishi reactions... |
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Dichloro-bis(aminophosphine) complexes of palladium: highly convenient, reliable and extremely active suzuki-miyaura catalysts with excellent functional group tolerance.
Chemistry 16(13) , 4075-81, (2010) Dichloro-bis(aminophosphine) complexes are stable depot forms of palladium nanoparticles and have proved to be excellent Suzuki-Miyaura catalysts. Simple modifications of the ligand (and/or the addition of water to the reaction mixture) have allowed their for... |
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Alkyne hydrothiolation catalyzed by a dichlorobis(aminophosphine) complex of palladium: selective formation of cis-configured vinyl thioethers.
Chemistry 18(29) , 8901-5, (2012) Cis all round: Dichlorobis[1-(dicyclohexylphosphanyl)piperidine]palladium, [(P{(NC(5)H(10))(C(6)H(11))(2)})(2)Pd(Cl)(2)], is a highly efficient alkyne hydrothiolation catalyst and the first generally applicable system that selectively generates cis-configured... |
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[Pd(Cl)2{P(NC5H10)(C6H11)2}2]--a highly effective and extremely versatile palladium-based Negishi catalyst that efficiently and reliably operates at low catalyst loadings.
Chemistry 16(36) , 11072-81, (2010) [Pd(Cl)(2){P(NC(5)H(10))(C(6)H(11))(2)}(2)] (1) has been prepared in quantitative yield by reacting commercially available [Pd(cod)(Cl)(2)] (cod=cyclooctadiene) with readily prepared 1-(dicyclohexylphosphanyl)piperidine in toluene under N(2) within a few minu... |
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Comparative Study of the Frech Catalyst with Two Conventional Catalysts in the Heck Synthesis of 2,4-Diaminopyrimidine-based Antibiotics.
Org. Prep. Proced. Int. 45(1) , 66-71, (2013)
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Access to 2-Aminopyridines - Compounds of Great Biological and Chemical Significance Bolliger, J. L.; et al.
Adv. Synth. Catal. 353 , 945, (2011)
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Mizoroki-Heck reactions catalyzed by dichloro{bis[1-(dicyclohexylphosphanyl)piperidine]}palladium. Palladium nanoparticle formation promoted by (water induced) ligand degradation. Oberholzer, M., et al.
Adv. Synth. Catal. 354 , 627, (2012)
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