Sodium pentafluoropropanoate

Sodium pentafluoropropanoate Structure
Sodium pentafluoropropanoate structure
Common Name Sodium pentafluoropropanoate
CAS Number 378-77-8 Molecular Weight 186.013
Density 1.64g/cm3 Boiling Point 93.5ºC at 760 mmHg
Molecular Formula C3F5NaO2 Melting Point 226-229 °C (dec.)(lit.)
MSDS USA Flash Point 10.3ºC

Improved liquid chromatographic method with pulsed electrochemical detection for the analysis of gentamicin.

J. Chromatogr. A. 1189(1-2) , 347-54, (2008)

The official method for the determination of the composition and related substances of gentamicin prescribed by the European Pharmacopoeia (Ph. Eur.) is liquid chromatography combined with pulsed electrochemical detection (LC-PED). However, this method utiliz...

Light-induced degradation of perfluorocarboxylic acids in the presence of titanium dioxide.

Chemosphere 67(4) , 785-92, (2007)

The UV-photon-induced degradation of heptafluorobutanoic acid was investigated in acidic aqueous solutions in the presence of titanium dioxide. Heptafluorobutanoic acid could be degraded with this photocatalyst in a light-induced reaction generating carbon di...

Application of perfluorinated acids as ion-pairing reagents for reversed-phase chromatography and retention-hydrophobicity relationships studies of selected beta-blockers.

J. Chromatogr. A. 1217(4) , 540-9, (2010)

The addition of the homologous series of perfluorinated acids-trifluoroacetic acid (TFAA), pentafluoropropionic acid (PFPA), heptafluorobutyric acid (HFBA) to mobile phases for reversed-phase high-performance liquid chromatography (RP-HPLC) of beta-blockers w...

Determination of fentanyl, metabolite and analogs in urine by GC/MS.

J. Appl. Toxicol. 31(7) , 649-54, (2011)

A rapid and sensitive method for the simultaneous determination of alfentanyl, sufentanyl and fentanyl (and its major metabolite norfentanyl) in urine was developed and validated. The method involved a liquid-liquid extraction in alkaline conditions, derivati...

Rational method development strategies on a fluorinated liquid chromatography stationary phase: mobile phase ion concentration and temperature effects on the separation of ephedrine alkaloids.

J. Chromatogr. A. 1095(1-2) , 113-8, (2005)

Fluorinated, silica-based stationary phases are becoming increasingly popular alternatives to traditional alkyl phases owing to their differential selectivity and retention for a variety of analyte classes. In this report, the ion-exchange mechanisms characte...

Determination of toluenediamine isomers by capillary gas chromatography and chemical ionization mass spectrometry with special reference to the biological monitoring of 2,4- and 2,6-toluene diisocyanate.

J. Chromatogr. A. 663(2) , 199-210, (1994)

The determination of 2,3-, 3,4-, 2,6-, 2,4- and 2,5-toluenediamine (TDA) in hydrolysed human urine and blood plasma was studied by GC-MS. The TDA isomers as their perfluoro-fatty acid anhydride derivatives were investigated. Chemical ionization with ammonia a...

Determination of N-methyl-1,3-propanediamine in bovine muscle by liquid chromatography with triple quadrupole and ion trap tandem mass spectrometry detection.

J. Chromatogr. A. 1235 , 103-14, (2012)

Morantel, pyrantel and their drug-related metabolites in food of animal-origin are regulated as sum of residues which may be hydrolysed to N-methyl-1,3-propanediamine (NMPA). In this study, an isotope dilution liquid chromatography tandem mass spectrometry (L...

One-dimensional coordination polymers incorporating silver(I) perfluorocarboxylate cuboctahedral clusters and the bis(methylthio)methane ligand.

Inorg. Chem. 46(8) , 3185-91, (2007)

Two topologically comparable complexes, [Ag6(CF3CO2)3(L1-Me)3(SCH3)3]infinity (1) and [Ag6(CF3CF2CO2)3(L1-Me)2(SCH3)3(H2O)]infinity (2), were prepared and characterized by single-crystal diffractometry. The structures consist of Ag12S6 clusters linked by bis(...

C-terminal sequencing of protein. A novel partial acid hydrolysis and analysis by mass spectrometry.

Eur. J. Biochem. 206(3) , 691-6, (1992)

Peptides or proteins were hydrolyzed by vapors of 90% pentafluoropropionic acid or heptafluorobutyric acid at 90 degrees C for various time periods. The hydrolyzate mixtures analyzed by both fast-atom-bombardment and electrospray ionization mass spectrometry ...

Context-dependent effects on the hydrophilicity/hydrophobicity of side-chains during reversed-phase high-performance liquid chromatography: Implications for prediction of peptide retention behaviour.

J. Chromatogr. A. 1125(2) , 211-9, (2006)

The present study set out to investigate whether observed relative hydrophilicity/hydrophobicity values of positively charged side-chains (with Lys and Arg as representative side-chains) or hydrophobic side-chains (with Ile as the representative side-chain) w...