![]() 4,4'-Bipyridine structure
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Common Name | 4,4'-Bipyridine | ||
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CAS Number | 553-26-4 | Molecular Weight | 156.184 | |
Density | 1.1±0.1 g/cm3 | Boiling Point | 304.8±0.0 °C at 760 mmHg | |
Molecular Formula | C10H8N2 | Melting Point | 109-112 °C(lit.) | |
MSDS | Chinese USA | Flash Point | 104.3±12.0 °C | |
Symbol |
![]() GHS06 |
Signal Word | Danger |
Embedment of Ag(I)-organic frameworks into silica gels for microextraction of polybrominated diphenyl ethers in soils.
J. Chromatogr. A. 1383 , 18-24, (2015) Three Ag(I)-organic frameworks, [Ag5(pydc)2(CN)]n, {[Ag4(pydc)2]CH3CN}n, and [Ag(4,4'-bpy)NO3]n, were synthesized and embedded into silica gels to form metal-organic-framework (MOF)-embedded gels for the microextraction of polybrominated diphenyl ethers (PBDE... |
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Direct identification of on-bead peptides using surface-enhanced Raman spectroscopic barcoding system for high-throughput bioanalysis.
Sci. Rep. 5 , 10144, (2015) Recently, preparation and screening of compound libraries remain one of the most challenging tasks in drug discovery, biomarker detection, and biomolecular profiling processes. So far, several distinct encoding/decoding methods such as chemical encoding, grap... |
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Synthesis, resolution, and absolute configuration of chiral 4,4'-bipyridines.
J. Org. Chem. 77(6) , 2579-83, (2012) A chiral polyhalogenated 4,4'-bipyridine derivative is described allowing an easy access to a new family of chiral 4,4'-bipyridines by site-selective cross-coupling reactions. The absolute configurations of all the HPLC separated enantiomers were determined b... |
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Template induced structural isomerism and enhancement of porosity in manganese(II) based metal-organic frameworks (Mn-MOFs).
Chem. Commun. (Camb.) 47(27) , 7674-6, (2011) Three new metal-organic framework isomers have been synthesized by using the organic linker 5-triazole isophthalic acid and Mn(NO(3))(2)·xH(2)O. Structural conversions from non-porous to porous MOFs due to the template effect have been observed. The cross-sec... |
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Rational design of two bpy-bridged 3D and 2D Co(II) open frameworks with similar amino-acid-based Schiff bases.
Dalton Trans. 41(47) , 14397-403, (2012) Two novel bpy-bridged Co(II) Schiff base complexes have been synthesized by the hydro(solvo)thermal reactions of corresponding amino-acid-based Schiff bases, bpy and Co(NO(3))(2)·6H(2)O. The following formulae identify the two complexes: {[Co(napala)(bpy)(0.5... |
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Coordination polymer nanobelts for nucleic acid detection.
Nanotechnology 22(19) , 195502, (2011) Herein, coordination polymer nanobelts (CPNBs) were prepared rapidly and on a large scale, by directly mixing aqueous AgNO(3) solution and an ethanol solution of 4, 4'-bipyridine at room temperature. The application of such CPNBs as a fluorescent sensing plat... |
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Synthesis, crystal structure and luminescent properties of one 3D Cd(II) coordination polymer [Cd(H3BPTC)2(bpy)]n (H4BPTC = 1,1'-biphenyl-2,2',6,6'-tetracarboxylic acid, bpy = 4,4'-bipyridine).
Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 81(1) , 764-8, (2011) A new 3D metal-organic coordination polymer [Cd(H(3)BPTC)(2)(bpy)](n) (1) (H(4)BPTC = 1,1'-biphenyl-2,2',6,6'-tetracarboxylic acid, bpy =4,4'-bipyridine) has been synthesized and characterized by single X-ray diffraction and IR spectroscopy. The one-dimension... |
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Antimicrobial activity of organotin(IV) complexes with the ligand benzil bis(benzoylhydrazone) and 4,4'-bipyridyl as coligand.
J. Inorg. Biochem. 105(5) , 600-8, (2011) Several methyltin(IV) and butyltin(IV) complexes with the ligand benzil bis(benzoylhydrazone) and 4,4'-bipyridyl as coligand were synthesised and characterized by elemental analysis and by IR, (1)H, (13)C and (119)Sn NMR spectroscopies. Some of them were also... |
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Rectangular coordination polymer nanoplates: large-scale, rapid synthesis and their application as a fluorescent sensing platform for DNA detection.
PLoS ONE 7(1) , e30426, (2012) In this paper, we report on the large-scale, rapid synthesis of uniform rectangular coordination polymer nanoplates (RCPNs) assembled from Cu(II) and 4,4'-bipyridine for the first time. We further demonstrate that such RCPNs can be used as a very effective fl... |
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Synthesis, structure, and properties of supramolecular charge-transfer complexes between bis(18-crown-6)stilbene and ammonioalkyl derivatives of 4,4'-bipyridine and 2,7-diazapyrene.
J. Org. Chem. 76(16) , 6768-79, (2011) 4,4'-Bipyridine and 2,7-diazapyrene derivatives (A) having two ammonioalkyl N-substituents were synthesized. The complex formation of these compounds with bis(18-crown-6)stilbene (D) was studied by spectrophotometry, cyclic voltammetry, (1)H NMR spectroscopy,... |