1,3-BIS(2,6-DIISOPROPYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE
1,3-BIS(2,6-DIISOPROPYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE structure
|
Common Name | 1,3-BIS(2,6-DIISOPROPYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE | ||
|---|---|---|---|---|
| CAS Number | 258278-25-0 | Molecular Weight | 427.065 | |
| Density | N/A | Boiling Point | N/A | |
| Molecular Formula | C27H39ClN2 | Melting Point | 289-293ºC(lit.) | |
| MSDS | Chinese USA | Flash Point | N/A | |
| Symbol |
GHS07 |
Signal Word | Warning | |
|
Palladium-(N-heterocyclic carbene) hydrogenation catalysts.
Angew. Chem. Int. Ed. Engl. 44 , 2026, (2005)
|
|
|
NHC-catalyzed ring expansion of oxacycloalkane-2-carboxaldehydes: a versatile synthesis of lactones.
Org. Lett. 11 , 891, (2009) Imidazolinium-derived carbenes catalyze the ring-expansion lactonization of oxacycloalkane-2-carboxaldehydes. A variety of functionalized five-, six-, and seven-membered lactones can be formed efficiently under mild reaction conditions. The success of this ne... |
|
|
Palladium-imidazolium carbene catalyzed Mizoroki-Heck coupling with aryl diazonium ions.
J. Org. Chem. 4 , 2079, (2002) [reaction: see text] Catalyst formed from N,N-bis(2,6-diisopropylphenyl)dihydroimidazolium chloride and palladium(II) acetate (2 mol %) was used, without added base, to efficiently produce Heck coupled products with olefins and aryl diazonium tetrafluoroborat... |
|
|
Synlett , 366, (2006)
|