Methanediamine,1-phenyl-N,N'-bis(phenylmethylene)-

Methanediamine,1-phenyl-N,N'-bis(phenylmethylene)- Structure
Methanediamine,1-phenyl-N,N'-bis(phenylmethylene)- structure
Common Name Methanediamine,1-phenyl-N,N'-bis(phenylmethylene)-
CAS Number 92-29-5 Molecular Weight 298.38100
Density 1.01 g/cm3 Boiling Point 422.6ºC at 760 mmHg
Molecular Formula C21H18N2 Melting Point 102-105ºC(lit.)
MSDS Chinese USA Flash Point 202ºC
Symbol GHS06
GHS06
Signal Word Danger

A simplified synthesis of (±)-1, 2-diphenyl-1, 2-diaminoethane (1) from benzaldehyde and ammonia. Revision of the structures of the long-known intermediates “hydrobenzamide” and “amarine”. Corey EJ and Kühnle FNM.

Tetrahedron Lett. 38(50) , 8631-34, (1997)

Synthesis and solution studies of Cu (II) complexes with pyridine derivatives of iminobisphosphonic acids. Goldeman W, et al.

Inorganica Chim. Acta 365(1) , 391-99, (2011)

An effective method to prepare imines from aldehyde, bromide/epoxide, and aqueous ammonia.

J. Org. Chem. 76(9) , 3511-4, (2011)

A three-component reaction of aldehydes, alkyl bromides, and ammonia to form imines was studied. Aqueous ammonia was applied as the nitrogen source and solvent in the reaction. For the aromatic aldehyde, the product yields are good to excellent and the reacti...